Aluminum Bonding via Zinc Eutectic Insert

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Solution Overview

Problem

Joining aluminum-based metals with a strong oxide film is challenging due to the high junction temperature required for eutectic reactions, which softens the base material and increases costs, especially when performed in an oxygen atmosphere.

Innovation Solution

Interposing an insert material with zinc and aluminum as main components between aluminum-based metal parts, causing a eutectic reaction at a lower temperature to melt and remove the oxide film, thereby bonding the metals at low temperature and pressure without flux.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high temperature heating is used to achieve eutectic reaction for joining aluminum-based metals, then the oxide film can be removed and bonding can be achieved, but the base material is softened and strength is lowered

Engineering Contradiction:
Improvejoining reliabilityVSAvoidbase material strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention changes the temperature parameter from conventional high temperature (above 500°C) to low temperature (300-450°C) by selecting specific eutectic alloy compositions. This allows the eutectic reaction to occur at temperatures that do not soften the base aluminum alloy, thereby maintaining base material strength while achieving reliable joining through oxide film removal.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite insert materials consisting of eutectic alloys (such as Al-Si, Al-Cu, or Al-Zn) with specific compositions. These composite materials enable the eutectic reaction to occur at controlled low temperatures, creating a multi-phase structure that removes oxide films effectively while preventing base material softening.

Inventive Principle:
Principle #40Composite materials

2Reliability

If heating to high temperature is performed for eutectic reaction, then oxide film removal is achieved, but thermal influence on surrounding areas increases causing distortion

Engineering Contradiction:
Improveoxide film removal efficiencyVSAvoidbase material shape stability
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

By changing the temperature parameter to low temperature range (300-450°C) through selective use of eutectic alloys, the invention achieves oxide film removal without causing significant thermal expansion or distortion of the base material, thereby maintaining shape stability while ensuring effective oxide film removal.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional eutectic joining is performed in oxygen atmosphere, then oxide film removal is effective, but specialized equipment and high costs are required

Engineering Contradiction:
Improveoxide film removal effectivenessVSAvoidequipment complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention introduces eutectic alloy inserts as intermediary materials that facilitate oxide film removal through chemical reaction at low temperatures. These inserts act as mediators between the base materials, enabling effective oxide film removal in atmospheric conditions without requiring complex vacuum or inert atmosphere equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The eutectic alloy inserts are consumed during the joining process to remove oxide films and facilitate bonding. These disposable insert materials (such as Al-Si, Al-Cu, or Al-Zn alloys) are relatively inexpensive and are sacrificed to achieve the joining objective, eliminating the need for expensive specialized equipment.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Reliability

If high temperature joining is used, then metallurgical bonding can be achieved, but the process becomes costly and time-consuming

Engineering Contradiction:
Improvemetallurgical bonding qualityVSAvoidjoining cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention changes the temperature parameter to low temperature (300-450°C) while maintaining effective metallurgical bonding through the eutectic reaction mechanism. This parameter change reduces both the time required for the joining process and the energy consumption, while still achieving reliable metallurgical bonds between aluminum-based metals.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for low-cost, low-temperature joining with minimal distortion and thermal impact on the base materials, preventing deformation and maintaining strength, while eliminating the need for specialized equipment.

Implementation Method 1

heating to a temperature that results in eutectic reaction is performed to produce the melt by way of eutectic reaction with Al in the base material at the joint interface of both materials

Methodology Applied
Scientific EffectEutectic reaction: Phase Change

Implementation Method 2

heating to the temperature that results in eutectic reaction is performed to produce the melt

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

both materials are pressed against each other, heating to the temperature that results in eutectic reaction is performed

Methodology Applied
Scientific EffectPressure: Pressure Increase

Data Source

PatentEP2612722B1Method for bonding aluminum-based metals
Publication Date: 2020.03.11 NISSAN MOTOR CO LTD
  • EP2612722B1 patent drawingFigure 1(a)~1(e)
  • EP2612722B1 patent drawingFigure 2~4
  • EP2612722B1 patent drawingFigure 5(a)~5(b)

AI summary

An inexpensive bonding method is provided with which it is possible to bond materials constituted of an aluminum-based metal to each other at a low temperature and a low pressure in the air while inhibiting deformation and without requiring the use of a flux and to minimize the influence on the base materials and on the periphery. Also provided are various bonded parts obtained by applying the bonding method. An insert material (2) comprising Zn as an element that undergoes a eutectic reaction with Al is interposed between two materials (1, 1) constituted of an aluminum-based metal. The two materials (1, 1) are heated, while being pressed against each other, to a temperature at which the eutectic reaction takes place, thereby generating, at the bonding interface between the two materials (1, 1), a melt due to the eutectic reaction with some of the Al contained in the base materials and discharging the Al oxide films (1a) from the bonding interface together with the melt. Thus, the two materials are bonded.