Amorphous Carbon Multilayer Electrode for OLED Radiation Extraction

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Solution Overview

Problem

Existing organic light-emitting diode (OLED) structures face complications in fabrication due to the need for additional electrode deposition and risk of impairing encapsulation functions, particularly with silicon-containing materials that pose hazards and have limited conductivity compared to amorphous carbon-based solutions.

Innovation Solution

The use of amorphous carbon multilayers for both electrodes, with refractive index differences achieved through varying deposition conditions rather than silane content, providing conductivity, encapsulation, and a Bragg mirror effect without silicon, allowing safer fabrication and improved radiation extraction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If silicon-containing materials are used to create refractive index differences in the encapsulating multilayer, then the optical characteristics are optimized, but the fabrication process becomes hazardous and the conductivity is limited

Engineering Contradiction:
Improveradiation extractionVSAvoidfabrication hazards
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material composition parameter from silicon-containing materials to amorphous carbon-based materials. This substitution eliminates fabrication hazards associated with silane while maintaining the ability to create refractive index differences through deposition condition variations, thus resolving the contradiction between optimized optical characteristics and safe fabrication

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating sublayers with different refractive indices within the amorphous carbon multilayer structure. By varying deposition conditions locally to produce regions with different optical properties, the patent achieves the necessary optical characteristics without requiring hazardous silicon-containing materials

Inventive Principle:
Principle #3Local quality

2Reliability

If an encapsulating multimirror layer is positioned in the lower position, then the encapsulation function is improved, but the fabrication process becomes more complicated requiring contact holes or vias

Engineering Contradiction:
Improveencapsulation functionVSAvoidfabrication process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies multi-functionality by designing the lower electrode as a multilayer structure that simultaneously provides electrical conduction and optical reflection functions. This eliminates the need for separate encapsulating multimirror layer with contact holes, thereby maintaining reliable encapsulation while simplifying the fabrication process

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the electrode function and the encapsulating mirror function into a single multilayer structure. By combining these two functions into one component, the patent eliminates the need for additional contact holes or vias through the encapsulating layer, thus reducing fabrication complexity while maintaining encapsulation reliability

Inventive Principle:
Principle #5Merging (Combining)

3Illumination intensity

If materials of different refractive indices are used in the encapsulating multilayer, then the Bragg mirror effect is enhanced, but the electrical conductivity is reduced due to insulating materials

Engineering Contradiction:
Improveradiation extractionVSAvoidelectrical conductivity
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent changes the material parameter from insulating materials to amorphous carbon-based materials that can provide both optical contrast and electrical conductivity. By maintaining the ability to create refractive index differences while using conductive materials, the patent resolves the contradiction between enhanced Bragg mirror effect and electrical conductivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite amorphous carbon structures with varying deposition conditions to create sublayers that exhibit both optical contrast (different refractive indices) and electrical conductivity. This composite approach allows simultaneous achievement of enhanced Bragg mirror effect and maintained conductivity

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the fabrication process, enhances radiation extraction, and maintains effective encapsulation without the hazards associated with silicon-containing materials, while ensuring high conductivity and optimized optical performance.

Implementation Method 1

The different refractive indices are obtained from the different deposition conditions and allow extraction of the radiation emitted by the organic electroluminescent layer

Methodology Applied
Scientific EffectBragg mirror effect: Bragg Diffraction

Implementation Method 2

acts as a diffusion barrier to certain elements from the substrate into the organic electroluminescent layer

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentEP1739764B1Light-emitting diode, one of the electrodes of which is a multilayer made of amorphous carbon
Publication Date: 2013.08.07 THOMSON LICENSING SA
  • EP1739764B1 patent drawingFigure 1

AI summary

Diode comprising a substrate (1) and an organic electroluminescent layer (3) interposed between a lower electrode and an upper electrode (4), at least one of which electrodes is formed from a multilayer (2) which is itself formed by the stack of adjacent sublayers (21, 22) made of amorphous carbon, having different refractive indices n1, n2. The amorphous carbon contains no added silicon, thereby making it possible to avoid using silane for the manufacture. The multilayer provides an electrode function, a multimirror function and an encapsulation function.