Amperometric Fuel Stability Detector for High-Temperature Testing

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Solution Overview

Problem

Current apparatuses for measuring fuel thermal stability are inefficient at temperatures above 275°C, lack real-time capability, and cannot quantify chemical species, leading to slow and unreliable results.

Innovation Solution

An apparatus with optical access, using a glass tube to enclose the fuel and provide heat, pressure control, and light measurement capabilities, allowing for real-time monitoring of fuel degradation and chemical species quantification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If current apparatuses are used for fuel thermal stability testing, then the testing can be performed, but the measurement reliability suffers when fuel temperature exceeds 275°C and cannot be performed when temperature exceeds 400°C

Engineering Contradiction:
Improvemeasurement reliabilityVSAvoidfuel temperature range
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent replaces mechanical/optical measurement systems with electrochemical sensing. The amperometric detector measures fuel degradation products through electrochemical reactions, enabling reliable measurement at temperatures up to 400°C where traditional optical methods fail due to soot interference and window fouling.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces an intermediary electrochemical detection system that measures degradation products rather than the fuel directly. This indirect measurement approach avoids the problems of direct optical measurement at high temperatures, where soot and deposits interfere with light transmission.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If current apparatuses are used for fuel thermal stability testing, then the testing can be performed, but the testing speed is slow taking several hours to deliver results

Engineering Contradiction:
Improvetesting speedVSAvoidtime to deliver results
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent implements continuous real-time monitoring of fuel degradation through the amperometric detector. The system continuously measures degradation products as they form, providing uninterrupted data flow and enabling immediate detection of thermal stability limits, reducing test time from hours to minutes.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent incorporates real-time feedback through the amperometric detection system that continuously monitors degradation products and provides immediate signal output. This feedback mechanism allows for rapid identification of thermal stability thresholds and eliminates the need for lengthy post-test analysis.

Inventive Principle:
Principle #23Feedback

3Loss of information

If current apparatuses are used for fuel thermal stability testing, then the testing can be performed, but the apparatus cannot quantify and qualify chemical species in real time

Engineering Contradiction:
Improvechemical species informationVSAvoidchemical species quantification capability
Core Design Contradiction:
Loss of informationVSMeasurement precision

Solution Approach 1:

The patent changes the detection parameter from optical properties to electrochemical properties. The amperometric detector measures the electrical current generated by electrochemical reactions of degradation products, enabling precise quantification and identification of chemical species based on their electrochemical signatures rather than optical characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time determination of fuel thermal stability and degradation rates, significantly improving performance by delivering accurate and timely data on fuel degradation and chemical species.

Implementation Method 1

optical detection system...deliver and collect light via fiber optics and/or free space couplings...measuring one or more properties of the delivered light and/or the collected light

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Data Source

PatentUS11906500B1Apparatus for measuring fuel thermal stability, deposit formation rate, and in-situ reactivity via optical methods
Publication Date: 2024.02.20 THE GOVERNMENT OF THE UNITED STATES AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
  • US11906500B1 patent drawing
  • US11906500B1 patent drawing
  • US11906500B1 patent drawing

AI summary

The present invention relates to apparatus for measuring fuel thermal stability, deposit formation rate, and in-situ reactivity via optical methods and as well as methods of making and using same. Applicants' apparatus can deliver the rate and amount of degradation as well as the quantifying and qualifying the chemical species in the fuel on a real time basis during a test. As a result, Applicants' apparatus provides significantly improved performance over the current apparatuses.