Aqueous Emulsion Pavement Primer Reducing VOC Emissions

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Solution Overview

Problem

Current priming materials for asphalt pavement, such as cutback asphalts and oil-in-water emulsions, contain volatile organic compounds (VOCs) that are harmful to the environment and may not adequately penetrate difficult base surfaces or repel moisture, leading to premature pavement deterioration.

Innovation Solution

Development of aqueous base-stabilized and acid-stabilized emulsions using polyamides, anionic or cationic emulsifiers, and solvents, which provide a VOC-free, penetrating, and hydrophobic coating for pavement surfaces, enhancing adhesion and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If cutback asphalts or oil-in-water emulsions with co-solvents are used for priming, then adhesion between base course and pavement material is improved, but volatile organic compounds (VOCs) are emitted causing environmental harm

Engineering Contradiction:
ImproveadhesionVSAvoidVOC emissions
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters by replacing VOC-containing solvents with water as the continuous phase in the emulsion. The asphalt is dispersed as fine droplets in water with the help of emulsifiers, creating a stable emulsion that cures to form an adhesive film without VOC emissions. This parameter change eliminates harmful emissions while maintaining the adhesion function.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite emulsion system combining asphalt (adhesive component), water (continuous phase), and emulsifiers (surface-active agents). This composite structure allows the asphalt to be delivered in a water-based vehicle that eliminates VOCs while the emulsifiers ensure proper spreading and adhesion. The composite nature enables both environmental compliance and functional performance.

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional priming materials are used, then adhesion is achieved, but penetration into difficult base surfaces is insufficient leading to premature deterioration

Engineering Contradiction:
ImproveadhesionVSAvoidpenetration
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the rheological parameters of the priming material by using a water-based emulsion with controlled viscosity and surface tension. The fine asphalt droplets in the emulsion can penetrate into porous and difficult base surfaces more effectively than conventional materials. The water-based vehicle evaporates leaving the asphalt bound in the substrate, achieving both penetration and adhesion.

Inventive Principle:
Principle #35Parameter changes

3Strength

If conventional priming materials are used, then adhesion is promoted, but moisture repulsion is insufficient causing structural failure

Engineering Contradiction:
ImproveadhesionVSAvoidmoisture resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the hydrophobicity parameter of the primed surface by using asphalt as the continuous adhesive phase that forms after water evaporation. The cured emulsion creates a hydrophobic barrier that repels moisture while maintaining strong adhesion to the base course. The asphalt binder provides both the adhesive bond and the moisture-resistant barrier in a single material system.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The emulsions offer improved penetration and moisture resistance, reducing VOC emissions and pavement failures, while being environmentally friendly and cost-effective, with rapid curing and resistance to cracking and separation.

Implementation Method 1

The emulsions offer improved penetration and moisture resistance

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

The polyamide comprises a condensation reaction product of an amine and a carboxylic acid or ester or anhydride thereof or an acyl halide

Methodology Applied
Scientific EffectCondensation reaction: Condensation

Implementation Method 3

provide a VOC-free, penetrating, and hydrophobic coating for pavement surfaces

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentUS11807759B2Emulsion compositions for priming a pavement surface
Publication Date: 2023.11.07 ECOLAB USA INC
  • US11807759B2 patent drawing

AI summary

Aqueous base- or acid-stabilized emulsions are provided for use on a pavement surface, and for use in an aqueous priming base emulsion that is used for priming a pavement surface. Any of the emulsions can be applied to a pavement surface to form a primed pavement surface, and then cured so that the pavement is available for use in preparing a pavement.