Battery Deplating Controller for Lithium Plating Removal

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Solution Overview

Problem

Lithium-ion batteries in electrified vehicles experience lithium plating when charged with currents exceeding design limits, leading to decreased capacity and increased cell resistance, potentially requiring battery replacement.

Innovation Solution

A method involving a controller that inhibits further charging and discharges the battery at a predetermined current for a defined duration to remove lithium from the anode, utilizing existing vehicle components like DC/DC converters and passive balance switches, and HVAC systems to manage the discharge process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If charge current exceeds design limit to increase charging speed, then productivity is improved, but lithium plating occurs on the anode causing battery capacity loss and increased cell resistance

Engineering Contradiction:
Improvecharging speedVSAvoidbattery capacity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The controller performs preliminary detection of charge current magnitude and duration before lithium plating occurs. When the charge current exceeds the threshold, the controller proactively commands a deplating discharge operation to remove plated lithium ions from the anode surface before they cause permanent capacity loss or resistance increase.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention converts the harmful effect of lithium plating into a beneficial process by using controlled deplating discharge. The plated lithium ions that would normally degrade battery performance are instead utilized as a source of discharge current, and the deplating process itself removes the harmful deposits while recovering capacity.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Productivity

If charge current exceeds design limit to increase charging speed, then productivity is improved, but cell resistance increases due to lithium plating

Engineering Contradiction:
Improvecharging speedVSAvoidcell resistance
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The controller detects charge current parameters in advance and commands deplating discharge operations before resistance significantly increases. This preliminary action prevents the accumulation of lithium plating that would otherwise cause irreversible resistance increase.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system implements feedback control by continuously monitoring charge current magnitude and duration, comparing against predefined thresholds, and automatically adjusting battery operations by commanding deplating discharge when thresholds are exceeded, thereby maintaining low cell resistance.

Inventive Principle:
Principle #23Feedback

3Reliability

If deplating discharge is commanded to remove lithium plating, then battery capacity is restored, but additional time is required beyond normal charging cycle

Engineering Contradiction:
Improvebattery capacityVSAvoidcharging cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The deplating discharge operation converts harmful lithium plating into useful discharge current. Instead of wasting time removing plating through idle processes, the system utilizes the plated lithium ions themselves as the discharge source, making the remediation process productive rather than purely corrective.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention merges the charging and deplating operations into a single integrated cycle. The deplating discharge is commanded immediately following high-current charging without requiring separate remediation time, effectively combining what would traditionally be two distinct operations into one continuous process.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If controller monitors charge current and commands deplating discharge to prevent lithium plating, then battery reliability is improved, but device complexity increases

Engineering Contradiction:
Improvebattery performanceVSAvoidcontrol system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The controller implements feedback control by monitoring charge current parameters, comparing them against predefined thresholds related to lithium plating occurrence, and automatically commanding deplating discharge operations when thresholds are exceeded. This closed-loop control maintains battery reliability through automated detection and correction.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The battery system performs self-service by using its own existing components (DC-DC converter, passive balance switch) to execute deplating discharge operations. The controller leverages already-present hardware resources rather than requiring additional dedicated deplating equipment, thereby maintaining reliability while minimizing complexity increase.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively removes lithium plating, reducing battery aging and cell resistance, allowing safe vehicle operation and extending battery life by using existing components to manage and control the discharge process.

Implementation Method 1

discharging the battery for a predetermined time at a predetermined current both defined by an amount and duration that the charge current exceeded the threshold to deplate lithium from an anode of the battery

Methodology Applied
Scientific EffectElectrochemical reaction: Battery (electricity)

Data Source

PatentUS10625627B2Method of remedying lithium plating in a high voltage battery
Publication Date: 2020.04.21 FORD GLOBAL TECH LLC
  • US10625627B2 patent drawing
  • US10625627B2 patent drawing

AI summary

A method for a vehicle comprises, by a controller, responsive to charge current for a battery exceeding a threshold, inhibiting further charging of the battery. The method further includes, responsive to the vehicle achieving a predefined state following the charge current exceeding the threshold, discharging the battery for a predetermined time at a predetermined current both defined by an amount and duration that the charge current exceeded the threshold to deplate lithium from an anode of the battery.