Biodegradable Hydrogel Actuator for Watertight Marine Shape Morphing

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Solution Overview

Problem

Existing soft robotic actuators for marine environments face challenges in being water-tight, exhibiting repeatable and reliable motion and force, and enabling design freedom, while also being non-biodegradable and potentially toxic.

Innovation Solution

Biodegradable actuators fabricated from calcium-alginate hydrogels sourced from brown seaweed, using a 3D printing process with a reversible chelation-crosslinking mechanism to tune mechanical properties and morphology, allowing for hydraulic or pneumatic actuation and safe deployment in marine ecosystems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If hydrogels are used as actuator material, then biodegradability and environmental safety are improved, but structural strength and water-tightness deteriorate

Engineering Contradiction:
Improveenvironmental safetyVSAvoidstructural strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent uses composite materials by combining hydrogel with reinforcement structures. The hydrogel provides biodegradability and environmental safety, while the reinforcement structures (such as porous polymer matrices or embedded frameworks) provide structural strength and water-tightness. This composite approach allows the actuator to simultaneously achieve environmental compatibility and mechanical integrity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs flexible shells and thin films to enclose the hydrogel actuator material. These shells provide water-tight sealing while maintaining the biodegradable characteristics of the hydrogel. The thin film structure protects the hydrogel from degradation by water and mechanical stress, enabling the actuator to function reliably in marine environments while remaining environmentally safe.

Inventive Principle:
Principle #30Flexible shells and thin films

2Adaptability or versatility

If hydrogels are extruded into fugitive support bath for embedded printing, then design freedom is improved, but manufacturing precision and reliability deteriorate

Engineering Contradiction:
Improvedesign freedomVSAvoidactuator performance consistency
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent introduces an intermediary substance or structure during the printing process. The fugitive support bath acts as an intermediary medium that enables the hydrogel to be extruded into complex geometries while maintaining structural integrity. This intermediary allows for design freedom in creating intricate actuator shapes while ensuring manufacturing precision through controlled support and removal processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs preliminary action by pre-preparing the hydrogel formulation and support bath conditions before printing. The hydrogel is pre-mixed with appropriate crosslinking agents and the support bath is pre-configured with optimal composition and concentration. This preliminary preparation ensures that during the printing process, the hydrogel maintains consistent properties and forms reliable actuators with repeatable performance, while still allowing for design freedom in the final structure.

Inventive Principle:
Principle #10Preliminary action

3Strength

If alginate actuators are crosslinked to increase stiffness, then structural integrity is improved, but morphing capability and adaptability deteriorate

Engineering Contradiction:
Improvestructural integrityVSAvoidmorphing capability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent applies dynamics by using dynamic crosslinking mechanisms that allow the alginate actuator to change its structural integrity based on operational needs. The crosslinking density can be adjusted or reconfigured during or after fabrication to provide the necessary stiffness for structural integrity while maintaining the ability to morph and adapt to different functional requirements. This dynamic adjustment enables the actuator to switch between rigid and flexible states as needed.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent utilizes parameter changes by modifying the crosslinking parameters of the alginate hydrogel. By controlling factors such as crosslinking concentration, temperature, and time, the actuator can be tuned to achieve the desired balance between structural integrity and morphing capability. The crosslinking parameters can be adjusted to provide sufficient stiffness for structural support while maintaining the flexibility needed for shape change and adaptation to different operational conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The actuators demonstrate consistent motion and force profiles over multiple cycles, with tunable stiffness and geometry, ensuring safe interaction with marine organisms and environmental safety through biodegradability.

Implementation Method 1

A reversible chelation-crosslinking mechanism can be used to dynamically modify the alginate actuators' structural stiffness and morphology

Methodology Applied
Scientific EffectChelation-crosslinking: Chemical Bonding

Implementation Method 2

the actuators are biodegradable, safely edible, and digestible by marine organisms

Methodology Applied
Scientific EffectBiodegradation: Decomposition (biological)

Data Source

PatentUS20250367838A1Biodegradable Hydrogel Actuator with Shape Morphing Capability for Soft Robotics and Methods of Fabrication
Publication Date: 2025.12.04 CARNEGIE MELLON UNIV
  • US20250367838A1 patent drawing
  • US20250367838A1 patent drawing
  • US20250367838A1 patent drawing

AI summary

A morphing, biologically-derived actuator can be used with soft robotics in a marine environment. The actuator is fabricated using a modified hydrogel additive manufacturing printing process, where the printed structure is exposed to various concentrations of crosslinking initiator to ensure a water-tight seal between adjacent printed layers. The actuator fabricated using the disclosed process is suitable for marine use and is safe for marine animals and is biodegradable.