Lithium-Ion Black Mass Extraction With Recycled Lithium Fractions

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Solution Overview

Problem

Hydrometallurgical processes for recovering metals from lithium-ion battery black mass face significant lithium losses, which need to be reduced to enhance recovery efficiency and simplify waste treatment.

Innovation Solution

A method involving leaching steps with recycled lithium-containing fractions, acid leaching using sulphuric acid, and metal separation processes, including solvent extraction and precipitation, to recover lithium and other transition metals like nickel, cobalt, and manganese, with a focus on recycling lithium precipitates to increase yield and reduce waste effluent lithium levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If conventional hydrometallurgical processes are used for metal separation, then transition metals can be recovered, but lithium losses occur during the process

Engineering Contradiction:
Improvelithium lossVSAvoidlithium recovery yield
Core Design Contradiction:
Loss of substanceVSProductivity

Solution Approach 1:

The patent applies the discarding and recovering principle by collecting lithium-containing fractions that would normally be discarded as waste effluents and recycling them back to the leaching step. This closes the material loop, preventing lithium loss and increasing overall recovery yield.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The patent implements feedback by monitoring lithium-containing fractions throughout the process and redirecting them back to the leaching step. This feedback mechanism ensures that lithium is continuously recovered and reused, minimizing losses and maximizing productivity.

Inventive Principle:
Principle #23Feedback

2Object-generated harmful factors

If metal separation steps are performed to recover transition metals, then valuable metals are obtained, but lithium ends up in waste effluents requiring treatment

Engineering Contradiction:
Improvelithium in waste effluentsVSAvoidwaste treatment complexity
Core Design Contradiction:
Object-generated harmful factorsVSEase of manufacture

Solution Approach 1:

The patent converts the harmful presence of lithium in waste effluents into a benefit by recycling these effluents back to the leaching step. What was previously a waste stream requiring treatment becomes a valuable source of recoverable lithium, eliminating the need for complex waste treatment.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Instead of discarding lithium-containing waste effluents to treatment facilities, the patent recovers and recyclers them back into the process, transforming a waste management problem into a resource recovery opportunity.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly increases lithium recovery yield, reduces lithium in waste effluents, and simplifies waste treatment by recycling lithium-containing fractions, thereby improving the overall efficiency and environmental impact of metal extraction from lithium-ion battery black mass.

Implementation Method 1

acid leaching to solubilize the cathode metals

Methodology Applied
Scientific EffectAcid leaching: Solvation

Implementation Method 2

acid leaching to solubilize the cathode metals, and prepare them for recovery

Methodology Applied
Scientific EffectChemical dissolution: Chemical Bonding

Data Source

PatentUS20240204277A1Extraction of metals from lithium-ion battery material
Publication Date: 2024.06.20 METSO OUTOTEC FINLAND OY
  • US20240204277A1 patent drawing
  • US20240204277A1 patent drawing
  • US20240204277A1 patent drawing

AI summary

A method for extracting metals from the black mass of lithium-ion batteries, the black mass containing the anode and cathode materials of the batteries, and the cathode material including lithium and nickel. An arrangement is provided that is suitable for use in the method.