Boric Acid Toner Composition for Low-Temperature Fixing

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Solution Overview

Problem

Existing toners struggle to achieve both low-temperature fixability and heat-resistant storage stability due to limitations in crystallinity and stability of vinyl-based crystalline resins, particularly when using copolymers with long-chain alkyl groups.

Innovation Solution

Incorporating boric acid into a toner particle comprising a binder resin with a side-chain crystalline polymer made from (meth)acrylic acid esters having linear alkyl groups of 18 to 36 carbon atoms, and optionally using boric acid salts like borax, enhances crystallinity and stability, ensuring both low-temperature fixability and heat-resistant storage stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a vinyl-based crystalline resin with long-chain alkyl groups is used as binder resin, then low-temperature fixability is improved, but sufficient crystallinity and heat-resistant storage stability cannot be achieved

Engineering Contradiction:
Improvefixing temperatureVSAvoidcrystallinity and storage stability
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The patent uses a copolymer binder resin combining vinyl-based crystalline resin segments with amorphous resin segments. This composite structure allows the crystalline segments to provide low-temperature fixability through their sharp melt property, while the amorphous segments contribute to overall stability and processability, resolving the contradiction between achieving low fixing temperature and maintaining sufficient crystallinity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by creating specific crystalline regions within the amorphous binder resin matrix. The vinyl-based crystalline resin forms localized crystalline domains that provide sharp melt behavior at low temperatures for fixing, while the surrounding amorphous matrix maintains general stability and prevents excessive crystallization that would harm storage properties

Inventive Principle:
Principle #3Local quality

2Temperature

If the glass transition temperature of binder resin is lowered to enable low-temperature fixing, then low-temperature fixability is improved, but heat-resistant storage stability deteriorates

Engineering Contradiction:
Improvefixing temperatureVSAvoidheat-resistant storage stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent exploits phase transitions by utilizing the sharp melt point of crystalline vinyl-based resin segments. These segments undergo a first-order phase transition (melting) at a specific temperature that is lower than conventional binders, enabling low-temperature fixing. The crystalline structure provides a defined melting behavior that allows low-temperature processing while maintaining stability below this melting point

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The copolymer structure combines segments with different thermal behaviors: the vinyl-based crystalline segments provide low-temperature melting for fixing, while the amorphous segments provide gradual transition and stability. This composite approach allows the binder to exhibit both low-temperature fixability and heat-resistant storage stability that cannot be achieved with single-phase binders

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The addition of boric acid improves the crystallinity of the side-chain crystalline resin, maintaining a sharp melt property and enhancing the toner's ability to fix at low temperatures while maintaining stability at high temperatures.

Implementation Method 1

the binder resin has a side-chain crystalline polymer B having a monomer unit A made of at least one polymerizable monomer A selected from the group consisting of (meth)acrylic acid esters having a linear alkyl group having 18 to 36 carbon atoms

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

the crystal melts rapidly at the melting point, and the melting is accompanied by a sharp drop in viscosity

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS12429789B2Toner and method for producing toner
Publication Date: 2025.09.30 CANON KK
  • US12429789B2 patent drawing
  • US12429789B2 patent drawing
  • US12429789B2 patent drawing

AI summary

A toner comprising a toner particle comprising a binder resin, wherein the binder resin has a side-chain crystalline polymer B having a monomer unit A made of at least one polymerizable monomer A selected from the group consisting of (meth)acrylic acid esters having a linear alkyl group having 18 to 36 carbon atoms, and the toner particle comprises boric acid.