Solid Electrolyte Capacitor Edge Polymer Thickness Control

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Solution Overview

Problem

Tantalum capacitors face reliability issues due to non-uniform polymer film thickness, which affects thermal stability and moisture resistance, making it difficult to achieve high-reliability and high-capacity devices.

Innovation Solution

A solid electrolyte capacitor design with a conductive polymer layer where the thickness ratio between the edge and central portions of the sintered body is controlled between 0.35 and 0.9, using a polymer slurry with conductive particles like graphene, carbon nanotubes, and carbon black to ensure uniformity and enhance thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polymer layer is applied above the sintered body, then the capacitor structure is formed, but the film thickness becomes non-uniform causing reliability deterioration

Engineering Contradiction:
Improvecapacitor reliabilityVSAvoidfilm thickness uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating different polymer layer thicknesses in different regions of the sintered body. The edge portion has a controlled thickness ratio (t2/t1) between 0.35 and 0.95, while the central portion has a different thickness. This non-uniform thickness distribution is intentionally designed to compensate for the coffee ring effect and improve overall reliability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the thickness parameter of the polymer layer in different regions. By controlling the thickness ratio (t2/t1) of the edge portion relative to the central portion within a specific range (0.35-0.95), the patent optimizes the film uniformity and prevents reliability deterioration caused by non-uniform thickness.

Inventive Principle:
Principle #35Parameter changes

2Temperature

If the polymer layer thickness is increased to improve reliability, then thermal stability improves, but moisture resistance deteriorates due to non-uniform distribution

Engineering Contradiction:
Improvethermal stabilityVSAvoidmoisture influence
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent addresses the contradiction between thermal stability and moisture resistance by applying different thicknesses of polymer layer in different regions. The controlled thickness ratio (t2/t1) ensures that the edge portion has sufficient thickness for thermal stability while maintaining appropriate thickness for moisture resistance, preventing the harmful effects of non-uniform distribution.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If the polymer layer is applied uniformly across the sintered body, then manufacturing is simplified, but edge and central portions have insufficient thickness control

Engineering Contradiction:
Improvepolymer application processVSAvoidthickness control in edge and central portions
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent resolves this contradiction by defining specific thickness requirements for different regions. The edge portion thickness (t2) is controlled to be 0.35-0.95 times the central portion thickness (t1), providing precise thickness control while maintaining a relatively simple manufacturing process.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The controlled thickness ratio improves thermal stability and reliability by reducing moisture influence, enabling the production of high-reliability and high-capacity tantalum capacitors with optimized edge and central polymer layer thickness.

Implementation Method 1

a sintered body formed by sintering a molded body containing metal powder

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

a conductive polymer layer disposed above the sintered body

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS11521801B2Solid electrolyte capacitor and fabrication method thereof
Publication Date: 2022.12.06 SAMSUNG ELECTRO MECHANICS CO LTD
  • US11521801B2 patent drawing
  • US11521801B2 patent drawing
  • US11521801B2 patent drawing

AI summary

A solid electrolyte capacitor includes a sintered body formed by sintering a molded body containing metal powder; and a conductive polymer layer disposed above the sintered body. A ratio (t2/t1) of a thickness (t2) of the conductive polymer layer in an edge portion of the sintered body to a thickness (t1) of the conductive polymer layer in a central portion of the sintered body satisfies 0.35≤t2/t1≤0.9.