Semiconductor Capacitor Interface Layer for Oxygen Loss

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Solution Overview

Problem

High surface energy of bottom electrodes in semiconductor capacitors leads to oxygen loss from dielectric layers, reducing capacitance and increasing leakage current, which is not effectively addressed by existing technologies.

Innovation Solution

A method for fabricating semiconductor devices with improved capacitors involves forming a bottom electrode with a high aspect ratio, followed by a sequential low-pressure plasma nitridation and high-pressure plasma oxidation process to create a uniform interface layer, reducing oxygen loss and enhancing capacitance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a bottom electrode with high surface energy is used in a capacitor, then the electrode can be formed with good adhesion and electrical properties, but oxygen is lost from the dielectric layer reducing capacitance and increasing leakage current

Engineering Contradiction:
Improvecapacitor reliabilityVSAvoidoxygen loss from dielectric layer
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

An interface layer is formed on the bottom electrode surface before depositing the dielectric layer. This preliminary action modifies the surface properties of the bottom electrode to reduce oxygen loss during subsequent dielectric layer formation and processing, thereby preventing oxygen loss while maintaining good adhesion and electrical properties

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

An interface layer is introduced as an intermediary between the bottom electrode and the dielectric layer. This interface layer acts as a barrier that prevents oxygen from the dielectric layer from being lost to the bottom electrode, while still allowing for good adhesion and electrical contact

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If a bottom electrode with high surface energy is used, then good adhesion is achieved, but leakage current increases due to oxygen loss

Engineering Contradiction:
Improveadhesion strengthVSAvoidleakage current
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

An interface layer is formed on the bottom electrode surface before depositing the dielectric layer. This preliminary action modifies the surface properties to achieve good adhesion while simultaneously reducing oxygen loss that causes leakage current

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

An interface layer is introduced as an intermediary between the bottom electrode and the dielectric layer, providing good adhesion while preventing oxygen loss that would otherwise increase leakage current

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in capacitors with low leakage current, improved capacitance, and excellent reliability by suppressing oxygen loss and stabilizing the dielectric layer, thus addressing the limitations of existing technologies.

Implementation Method 1

performing the first plasma process in an ion plasma-dominant atmosphere at a low pressure

Methodology Applied
Scientific EffectPlasma nitridation: Plasma

Implementation Method 2

performing the first plasma process in a nitrogen ion plasma-dominant atmosphere

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 3

performing the second plasma process in a radical plasma-dominant atmosphere at a high pressure

Methodology Applied
Scientific EffectPlasma oxidation: Plasma

Implementation Method 4

the second plasma process may include a high-pressure plasma oxidation

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS10910383B2Semiconductor device and method for fabricating the same
Publication Date: 2021.02.02 SK HYNIX INC
  • US10910383B2 patent drawing
  • US10910383B2 patent drawing
  • US10910383B2 patent drawing

AI summary

A method for fabricating a semiconductor device includes: forming a bottom electrode of a high aspect ratio; forming an interface layer by sequentially performing a first plasma process and a second plasma process onto a surface of the bottom electrode; forming a dielectric layer over the interface layer; and forming a top electrode over the dielectric layer.