Carbide Refining in High-Carbon High-Alloy Steel via Spray Forming

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Solution Overview

Problem

High-carbon high-alloy steel tends to form coarse eutectic carbides and experiences serious segregation, leading to non-uniform structures that restrict its mechanical properties and wear resistance, with existing manufacturing methods like conventional casting and electroslag remelting failing to effectively address these issues.

Innovation Solution

A carbide refining method involving overheat treatment of high-carbon high-alloy molten steel followed by deposition in a water-cooled copper mold under inert gas, combined with a specific heat treatment process, to achieve a dense structure with fine carbides, improving the microstructure and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional casting method or electroslag remelting method is used, then large-batch industrial production is achieved, but coarse eutectic carbides form and serious segregation occurs

Engineering Contradiction:
Improvelarge-batch industrial productionVSAvoidcarbide refinement and composition uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies rapid solidification by changing the cooling rate parameter from conventional slow cooling to extremely fast cooling (10^3-10^6 K/s). This parameter change transforms the solidification process, preventing carbide precipitation and segregation that occur in conventional methods, thereby achieving fine microstructure and uniform composition while maintaining industrial production capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent transitions from conventional bulk solidification to a spray-based process where molten metal is atomized into droplets. This dimensional change from bulk to dispersed droplet form enables rapid heat extraction and uniform cooling throughout the material, eliminating the carbide formation and segregation problems inherent in conventional casting while maintaining productivity

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Manufacturing precision

If spray forming method is used, then structure refinement and composition uniformity are achieved, but yield is low and loose structure with inherent pores forms

Engineering Contradiction:
Improvestructure refinement and composition uniformityVSAvoidyield
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent utilizes controlled phase transition from liquid to solid through rapid cooling. By managing the liquid-to-solid transition in a controlled spray atmosphere with optimized cooling rates, the method achieves dense structure formation without the pores and loose structure characteristic of conventional spray forming, while maintaining high productivity through efficient material utilization

Inventive Principle:
Principle #36Phase transitions

3Speed

If degree of overheat is too high, then fluidity is improved for rapid impact, but grains of solidified structure become coarse

Engineering Contradiction:
Improvefluidity for rapid impactVSAvoidgrain size of solidified structure
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent employs dynamic control of the heating and cooling process. The molten metal is heated to a precise temperature range to achieve optimal fluidity for spray atomization, then immediately subjected to rapid cooling. This dynamic approach maintains the balance between fluidity requirements for processing and grain refinement requirements for final structure, preventing both insufficient fluidity and excessive grain growth

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a high-carbon high-alloy steel with a dense and uniform microstructure, refined carbides, enhanced strength, toughness, and wear resistance, thereby improving the service lifetime of the steel.

Implementation Method 1

making the high-carbon high-alloy melt deposited in a preset water-cooled copper mold at a speed of 30 ̃160 g/s by an inert gas, to obtain a high-carbon high-alloy billet through solidification molding

Methodology Applied
Scientific EffectHeat extraction and solidification: Cooling

Implementation Method 2

making the high-carbon high-alloy melt deposited in a preset water-cooled copper mold at a speed of 30 ̃160 g/s by an inert gas

Methodology Applied
Scientific EffectGas pressure-driven flow: Pressure Gradient

Implementation Method 3

in the subsequent heat treatment process, the grains are recrystallized on the basis of dislocation and fragmented primary carbides, to achieve fine grains, fine carbides, and uniform distribution

Methodology Applied
Scientific EffectHeat treatment and recrystallization: Heat Treatment

Data Source

PatentUS20240167135A1Carbide refining method of high-carbon high-alloy steel
Publication Date: 2024.05.23 SHANGHAI JIAOTONG UNIV
  • US20240167135A1 patent drawing
  • US20240167135A1 patent drawing
  • US20240167135A1 patent drawing

AI summary

The present disclosure provides a carbide refining method of a high-carbon high-alloy steel. The carbide refining method of a high-carbon high-alloy steel includes the following steps: formulating a raw material according to chemical element compositions of the high-carbon high-alloy steel, and smelting to obtain a high-carbon high-alloy molten steel; performing an overheat treatment on the high-carbon high-alloy molten steel to Tm+(50˜100)° C., to obtain a high-carbon high-alloy melt, and making the high-carbon high-alloy melt to be deposited in a preset water-cooled copper mold at a speed of 30˜160 g/s by an inert gas, to obtain a high-carbon high-alloy billet through solidification molding; and performing a heat treatment process on the high-carbon high-alloy billet.