Cathode Surface Area Expansion via Conductive Ink Printing

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Solution Overview

Problem

Conventional electrolytic capacitors, particularly in implantable cardioverter defibrillators, face limitations in capacitance due to the lower surface area of cathodes compared to anodes, leading to reduced energy density and increased size, and the use of titanium nitride coatings complicates manufacturing with connection issues and higher costs.

Innovation Solution

A method using commercially available printing technologies to deposit a high surface area coating on metal foils, specifically conductive ink with nanoparticles, precisely on cathode plates, avoiding areas like tabs and cutting edges, followed by sintering to increase cathode surface area without the manufacturing complexities of titanium nitride.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional aluminum foil cathodes are used in electrolytic capacitors, then the manufacturing process is simple, but the cathode surface area is insufficient compared to anodes, limiting capacitance and energy density

Engineering Contradiction:
Improvecathode surface areaVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent applies porous materials by coating the cathode foil with a layer containing porous particles (such as metal oxides, hydroxides, or carbonaceous materials). These porous structures dramatically increase the cathode surface area, enabling it to match or exceed the anode surface area, thereby increasing capacitance and energy density without complicating the manufacturing process

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses composite materials by combining conductive materials (such as graphite, carbon black, or metal powders) with porous materials (metal oxides, hydroxides, or carbonaceous materials) in a binder matrix. This composite structure provides both electrical conductivity and high surface area, resolving the contradiction between simple manufacturing and increased cathode surface area

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If titanium nitride coatings are applied to increase cathode surface area, then capacitance improves, but manufacturing complexity increases due to connection issues and higher costs

Engineering Contradiction:
Improvecathode surface areaVSAvoidmanufacturing ease
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent replaces titanium nitride coatings with porous particle coatings (metal oxides, hydroxides, or carbonaceous materials). These porous materials achieve high surface area through their intrinsic pore structures rather than requiring complex thin-film deposition processes, thereby maintaining ease of manufacture while increasing cathode surface area and capacitance

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent changes the fundamental approach from applying dense thin-film coatings (titanium nitride) to using loose porous particle coatings. This parameter change in coating structure and application method simplifies manufacturing while achieving the desired high surface area, eliminating connection issues associated with titanium nitride

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If capacitor size is reduced for implantable devices, then energy density must increase, but conventional cathode designs cannot provide sufficient capacitance per unit volume

Engineering Contradiction:
Improveenergy densityVSAvoidcapacitor volume
Core Design Contradiction:
Quantity of substanceVSVolume of moving object

Solution Approach 1:

The patent applies porous materials to the cathode surface, creating a three-dimensional high-surface-area structure within a thin coating layer. This enables the cathode to provide sufficient capacitance in a compact form factor, allowing reduced capacitor volume while maintaining or increasing energy density for implantable medical devices

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent implements a nested structure by placing porous particles and composite materials within a binder matrix coating on the cathode foil. This nested arrangement maximizes surface area within a limited thickness, enabling high energy density in compact capacitors suitable for implantable devices

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances cathode capacitance, increases energy density, simplifies production, reduces costs, and minimizes connection issues, enabling more compact high-capacity capacitors.

Implementation Method 1

A method using commercially available printing technologies to deposit a high surface area coating on metal foils, specifically conductive ink with nanoparticles

Methodology Applied
Scientific EffectPrinting deposition: Deposition (physical)

Implementation Method 2

The solvent evaporates, leaving behind a coating on the metal foil

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

followed by sintering to increase cathode surface area

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS10573467B2Method of printing a conductive ink onto a cathode surface to increase surface area and capacitance
Publication Date: 2020.02.25 PACESETTER INC
  • US10573467B2 patent drawing
  • US10573467B2 patent drawing
  • US10573467B2 patent drawing

AI summary

A method of processing a metal foil to produce a cathode for an electrolytic capacitor includes printing one or more layers of conductive ink on the metal foil to form a pattern of cathode plates, each of the one or more layers being a predetermined thickness, and the pattern arranged at a distance from a cathode tab and an edge of the cathode plates. The method also includes heating the deposited one or more layers of conductive ink to evaporate a solvent within the conductive ink such that conductive particles of the conductive ink remain deposited on the metal foil. The method further includes sintering the conductive particles and cutting the cathode plates from the metal foil, thereby producing the cathode plates suitable for use in the electrolytic capacitor.