Cement Activator Composition Stabilizer Polymer

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Solution Overview

Problem

Existing cement activating compositions for subterranean cementing operations often require immediate preparation and have stability issues, leading to operational disruptions and limited storage and transportation flexibility due to separation or gelling within 24 hours, which restricts their use and effectiveness.

Innovation Solution

A liquid cement activator composition comprising water, an alkali sulfate salt, a polyphosphate salt, and a stabilizer polymer that maintains homogeneity and prevents gelling for extended periods, allowing for pre-formulation and storage, and can activate cement compositions at lower temperatures, while also providing fluid loss control properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If many activating compositions are used to accelerate cement curing, then cement setting speed is improved, but the composition separates or gels within 24 hours requiring immediate preparation

Engineering Contradiction:
Improvecement setting speedVSAvoidactivating composition stability
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The activating composition is prepared in advance and stored for extended periods (months to years) before use. The composition includes a stabilizer component that prevents separation and gelling during storage, allowing the cement slurry to be activated at the desired time rather than requiring immediate preparation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A stabilizer component acts as an intermediary substance that prevents the activating composition from separating or gelling during storage. This stabilizer maintains the homogeneous dispersion of the composition until activation is desired, bridging the gap between preparation and use.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If activating compositions are prepared immediately prior to use, then composition stability is maintained, but operational disruptions occur due to need for on-location preparation

Engineering Contradiction:
Improveactivating composition stabilityVSAvoidoperational efficiency
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The activating composition is prepared in advance and stored for extended periods (months to years) before use. The composition includes a stabilizer component that prevents separation and gelling during storage, allowing the cement slurry to be activated at the desired time rather than requiring immediate preparation.

Inventive Principle:
Principle #10Preliminary action

3Duration of action of stationary object

If set-delayed cement compositions are used for extended storage, then pumpability is maintained at room temperature, but activation and curing become challenging

Engineering Contradiction:
Improvestorage durationVSAvoidactivation ease
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The activating composition is designed to change its parameters (reactivity, pH, temperature sensitivity) upon activation. The composition includes components that remain stable during storage but become highly reactive when activated, enabling easy activation after extended storage periods through simple triggers such as temperature increase or chemical mixing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures stability and homogeneity for longer periods, enabling on-site preparation and transportation, and allows for effective activation of cements at lower temperatures, reducing operational disruptions and enhancing cementing operations by maintaining cement slurry stability and fluid loss control.

Implementation Method 1

a stabilizer polymer that maintains homogeneity and prevents gelling for extended periods

Methodology Applied
Scientific EffectSteric stabilization:

Implementation Method 2

The variable AG can be the anionic group

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Implementation Method 3

an alkali sulfate salt, a polyphosphate salt... that can activate cement compositions at lower temperatures

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

providing fluid loss control properties

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11535788B2Cement activator composition for treatment of subterranean formations
Publication Date: 2022.12.27 HALLIBURTON ENERGY SERVICES INC
  • US11535788B2 patent drawing
  • US11535788B2 patent drawing
  • US11535788B2 patent drawing

AI summary

Various embodiments disclosed relate to cement activator compositions for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation including placing in the subterranean formation a liquid cement activator composition including water, an alkali sulfate salt, a polyphosphate salt, and a stabilizer polymer.