Ceramic Injection Element for FCC Regenerator Nozzle Erosion

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Solution Overview

Problem

The existing gas injection systems in fluid catalytic cracking (FCC) units face issues with nozzle erosion due to catalyst abrasion, leading to frequent maintenance needs and potential performance degradation, despite improvements like titanium nitride coatings and composite nozzles, there is a need for a more durable and low-maintenance solution.

Innovation Solution

The use of ceramic injection elements, specifically made from high-hardness materials like silicon carbide, which are designed to withstand abrasion and thermal stress, allowing for optimized gas distribution and reduced maintenance requirements, with a focus on ceramic matrix composites (CMCs) for enhanced durability and reduced weight.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If steel nozzles with titanium nitride coating are used, then erosion resistance is improved, but the nozzles still fail rapidly when coating is eroded and require regular replacement

Engineering Contradiction:
Improvenozzle erosion resistanceVSAvoidnozzle service life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The invention uses ceramic materials (such as alumina, silicon carbide, or silicon nitride) to manufacture the entire injection element, creating a composite structure that combines the benefits of ceramic hardness and erosion resistance with appropriate mechanical properties. This eliminates the need for metal nozzles with ceramic coatings, providing sustained erosion resistance throughout the entire nozzle service life without the rapid failure that occurs when the coating is depleted.

Inventive Principle:
Principle #40Composite materials

2Reliability

If regular nozzle replacement is performed, then performance degradation is prevented, but maintenance frequency and operational downtime increase

Engineering Contradiction:
Improveregenerator performanceVSAvoidmaintenance downtime
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention employs ceramic injection elements that are designed to be durable and long-lasting, replacing the need for frequent replacement of shorter-lived metal nozzles. The ceramic material's inherent erosion resistance allows these elements to maintain performance throughout extended operational periods, reducing maintenance frequency and associated downtime.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If thicker erosion-resistant coatings are deposited, then durability is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvenozzle durabilityVSAvoidnozzle manufacturing simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

Instead of depositing thick erosion-resistant coatings on metal nozzles, the invention manufactures the entire injection element from ceramic material using ceramic forming and sintering processes. This eliminates the multi-step coating deposition process and provides inherent erosion resistance throughout the entire nozzle structure, simplifying manufacturing while maximizing durability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ceramic injection elements provide improved resistance to catalyst abrasion, reducing maintenance needs, optimizing gas distribution, and maintaining catalyst quality, while being lighter and potentially requiring fewer nozzles, thus enhancing the operational reliability and efficiency of the FCC unit.

Implementation Method 1

The erosion of the steel by the catalyst is indeed capable of leading to a failure of the injection nozzles and/or, in particular when catalyst goes back inside the nozzles, an abrasion of the inner walls of the nozzles

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 2

The temperature in the regenerator is of the order of 600°C to 700°C

Methodology Applied
Scientific EffectThermal stress: Thermal Expansion

Data Source

PatentEP3174626B1Element for injecting gas into a regenerator of a fluid catalytic cracking unit
Publication Date: 2019.08.28 TOTAL RAFFINAGE CHIM
  • EP3174626B1 patent drawingFigure 1~3

AI summary

An injection element (10) for a gas injection system (1) inside a regenerator of a fluid catalytic cracking unit, said injection element defining a flow passage (12) and being arranged so as to be able to be fastened to a support (11) so that said flow passage opens on one side into a cavity and on the other side into a fluidized catalyst bed,characterized in that said injection element is made of ceramic material with ceramic and / or carbon fibres.