Charge-Trapping Memory Cells with Additives for Better Retention

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Solution Overview

Problem

Charge-trapping-material in memory cells often has too many shallow traps, leading to poor charge retention, which is a challenge in maintaining data storage reliability in flash memory devices like NAND memory arrays.

Innovation Solution

Incorporating trap-enhancing-additives such as carbon, boron, phosphorus, or metal into the charge-trapping-material, specifically silicon nitride, to modify trap depths and increase trap density while maintaining desired retention properties, thereby enhancing charge retention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional charge-trapping-material is used in memory cells, then the device structure is simple and manufacturing is easier, but the charge retention is poor due to too many shallow traps

Engineering Contradiction:
Improvecharge retentionVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining silicon nitride with trap-enhancing additives (carbon, boron, phosphorus, or metal) to create a composite charge-trapping-material. This composite structure provides both the structural framework of silicon nitride and the trap-depth modification from the additives, resolving the contradiction between simple structure and improved charge retention.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameters of the charge-trapping-material by incorporating specific concentrations of trap-enhancing additives (e.g., carbon at 0.2-20 atomic percent, boron at 0.2-20 atomic percent). This parameter modification transforms the trap depth distribution from shallow-dominated to deeper-trap-enriched, improving charge retention while maintaining manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If trap-enhancing-additives are incorporated into charge-trapping-material, then charge retention is improved through deeper traps, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvecharge retentionVSAvoidmaterial fabrication difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-mixing the trap-enhancing additives with the silicon nitride material before deposition. This preliminary preparation allows the additives to be uniformly distributed in the source material, simplifying the subsequent deposition process and making the enhanced manufacturing complexity manageable through advance preparation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The trap-enhancing additives serve as intermediaries that mediate between the silicon nitride matrix and the charge storage function. These additive elements (carbon, boron, phosphorus, or metal) act as intermediate components that modify the electronic structure and trap depth without requiring complete restructuring of the material system, thus limiting the increase in manufacturing complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The incorporation of trap-enhancing-additives within the charge-trapping-material improves charge retention by creating deeper traps, addressing the issue of shallow traps and enhancing the overall performance of memory cells in NAND memory devices.

Implementation Method 1

charge-trapping-material includes silicon, nitrogen and trap-enhancing-additive... improves charge retention by creating deeper traps

Methodology Applied
Scientific EffectCharge trapping: Potential Well

Data Source

PatentUS20240297257A1Memory Cells and Integrated Assemblies having Charge-Trapping-Material with Trap-Enhancing-Additive
Publication Date: 2024.09.05 MICRON TECHNOLOGY INC
  • US20240297257A1 patent drawing
  • US20240297257A1 patent drawing
  • US20240297257A1 patent drawing

AI summary

Some embodiments include a memory cell having charge-trapping-material between a semiconductor channel material and a gating region. The charge-trapping-material includes silicon, nitrogen and trap-enhancing-additive. The trap-enhancing-additive includes one or more of carbon, phosphorus, boron and metal. Some embodiments include an integrated assembly having a stack of alternating first and second levels. The first levels include conductive structures and the second levels are insulative. Channel-material-pillars extend through the stack. Charge-trapping-regions are along the channel-material-pillars and are between the channel-material-pillars and the conductive structures. The charge-trapping-regions include a charge-trapping-material which contains silicon, nitrogen and trap-enhancing-additive. The trap-enhancing-additive includes one or more of carbon, phosphorus, boron and metal.