Time-Resolved Charged Particle Microscopy Using a Liquifiable Barrier

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Solution Overview

Problem

Existing charged particle microscopy methods for studying (bio)chemistry experiments are limited by the need for complex micro-reactors that are not fully transparent to electrons, making time-resolved observations of chemical reactions challenging and time-consuming.

Innovation Solution

A method using a liquifiable barrier material, such as vitreous ice, is introduced to separate and then allow interaction between particles, enabling time-resolved observations by locally heating or using a charged particle beam to liquify the barrier, followed by re-solidification for detailed imaging.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If micro-reactors are used to observe particles in fluid, then spatial detail of chemical reactions can be studied, but device complexity increases and transparency to electrons is reduced

Engineering Contradiction:
Improvespatial detailVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention extracts and removes the complex micro-reactor structure entirely, replacing it with a simple liquid layer on a grid. This eliminates the transparency problems and complexity while maintaining the ability to observe particle interactions in fluid, directly resolving the contradiction between measurement precision and device complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Instead of using complex physical micro-reactors, the invention creates a simplified copy of the fluid environment using a thin liquid layer on a standard grid. This copy maintains the essential function of containing fluid and particles while being fully transparent to electrons and much simpler in structure.

Inventive Principle:
Principle #26Copying

2Measurement precision

If micro-reactors are used for time-resolved observations, then chemical reactions can be studied, but observation time increases due to complexity

Engineering Contradiction:
Improvetime resolutionVSAvoidobservation time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

By removing the complex micro-reactor structure, the invention eliminates the time-consuming setup and preparation associated with these devices. The simplified system allows rapid implementation of time-resolved observations, directly reducing the total observation time while maintaining high time resolution capability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention performs preliminary action by freezing the liquid layer containing particles before observation. This pre-preparation step creates a stable, preservable state that can be quickly imaged, eliminating the need for complex real-time maintenance during observation and reducing total observation time.

Inventive Principle:
Principle #10Preliminary action

3Adaptability or versatility

If barrier material is used to separate particles, then particle interactions can be controlled, but additional materials and complexity are introduced

Engineering Contradiction:
Improveparticle interaction controlVSAvoidstructure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The invention controls particle interactions by changing the physical state parameter of the liquid layer (freezing to separate, melting to enable interaction). This eliminates the need for solid barrier materials and their associated complexity, while maintaining full adaptability to control when particles interact by simply controlling the temperature state.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The liquid layer serves multiple functions simultaneously: it separates particles when frozen, enables their interaction when melted, provides a medium for Brownian motion, and preserves the sample structure. This self-service multi-functionality eliminates the need for separate barrier materials and reduces overall structural complexity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for improved time-resolved charged particle microscopy without the need for expensive micro-reactors, providing detailed spatial and temporal insights into chemical interactions with high temporal resolution.

Implementation Method 1

liquifying at least a part of the barrier material for enabling an interaction between the first particle and the second particle

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

liquifying at least a part of the barrier material

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

observing the resulting interaction between the first particle and the second particle in a charged particle microscope

Methodology Applied
Scientific EffectElectromagnetic interaction:

Data Source

PatentEP4679068A1Method of time-resolved charged particle microscopy
Publication Date: 2026.01.14 FEI CO
  • EP4679068A1 patent drawingFigure 1
  • EP4679068A1 patent drawingFigure 2~3
  • EP4679068A1 patent drawingFigure 4a~4c

AI summary

The invention relates to a method of time-resolved charged particle microscopy, comprising the step of providing a sample for charged particle microscopy, wherein said sample comprises a first particle and a second particle, and wherein said sample comprises a barrier material between said first particle and said second particle. The method further comprises the step of liquifying at least a part of the barrier material for enabling an interaction between the first particle and the second particle. Finally, the resulting interaction between the first particle and the second particle can be observed in a charged particle microscope.