Chromium Carbide Coating for Aircraft Engine Erosion Resistance

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Solution Overview

Problem

Aircraft engine parts face erosion damage due to ingested particles, and existing coatings lack sufficient hardness and are unsuitable for complex shapes or high temperatures, with known methods being inefficient or time-consuming.

Innovation Solution

A chromium-based coating with Cr7C3 and Cr23C6 carbides, formed through a heat treatment process using a chromium and carbon composition, providing enhanced hardness and adhesion, and optionally including metal or ceramic particles, applied via electroplating for complex shapes and improved uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If metal nitrides are deposited by PVD or CVD, then the coating presents good hardness, but the coating cannot withstand high temperatures and cannot coat complex shapes

Engineering Contradiction:
ImprovehardnessVSAvoidtemperature resistance and shape adaptability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The invention changes the chemical composition parameters of the coating by incorporating chromium and carbon in specific ratios (Cr: 6-13 wt%, C: 2-4 wt%) to form chromium carbides that provide both hardness and temperature resistance. The deposition parameters are also optimized to achieve the desired microstructure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating structure containing chromium carbides (Cr7C3, Cr23C6) embedded in a metal matrix, combining the hardness benefits of carbides with the temperature resistance and ductility of the metal substrate, achieving both PVD/CVD-like hardness and plasma spraying-like temperature resistance

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If hexavalent chromium coating is deposited by electrodeposition, then complex shapes can be coated, but the coating lacks sufficient hardness for erosion resistance

Engineering Contradiction:
Improveshape adaptabilityVSAvoidhardness
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The invention changes the composition parameters by adding carbon (2-4 wt%) to the chromium-based coating, which transforms the microstructure during heat treatment to form hard chromium carbides, thereby increasing hardness while preserving the electrodeposition capability to coat complex shapes

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If chromium and chromium carbides are deposited by plasma spraying with long heat treatment, then erosion resistance is improved, but the process is time-consuming and unsuitable for complex shapes

Engineering Contradiction:
Improveerosion resistanceVSAvoidheat treatment duration
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The invention optimizes the composition parameters (Cr: 6-13 wt%, C: 2-4 wt%) to enable rapid formation of chromium carbides during heat treatment, reducing the required heat treatment time from over 200 hours to just 2-8 hours while achieving the same erosion resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention performs preliminary alloying during the deposition stage by incorporating carbon into the chromium coating, so that the subsequent heat treatment only needs to facilitate carbide precipitation rather than forming the entire coating structure, significantly reducing treatment time

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves high hardness exceeding 1500 HV and effective erosion resistance for aircraft engine parts, with reduced heat treatment duration and ability to coat complex shapes, while maintaining mechanical strength.

Implementation Method 1

said coating composition being deposited on the metal substrate in a step of electroplating

Methodology Applied
Scientific EffectElectroplating: Electrodeposition

Implementation Method 2

a step of heat treating the coating for a duration of longer than 200 hours (h)

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

applying heat treatment serves to reinforce the coating that has been formed by causing the Cr7C3 and Cr23C6 carbides to precipitate

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentUS10753006B2Aircraft engine part including a coating for protection against erosion, and a method of fabricating such a part
Publication Date: 2020.08.25 SAFRAN HELICOPTER ENGINES
  • US10753006B2 patent drawing
  • US10753006B2 patent drawing

AI summary

An aircraft engine-part including at least a metal substrate and a protective coating for protection against erosion that is present on the substrate, the coating including at least one phase including at least chromium at an atom content greater than or equal to 45% and carbon at an atom content lying in the range 5% to 20%, the phase including Cr7C3 and Cr23C6 chromium carbides. A method of fabricating such a part in which electroplating is used to deposit a coating composition on the part and the part is subjected to heat treatment at a temperature lying in the range 250° C. to 70° C.