CMOS Image Sensor Photodiode Wells via Cryogenic Ion Channeling

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Solution Overview

Problem

Existing CMOS image sensors face limitations in photodiode well depth due to the maximum energy of existing ion implanters and degradation of ion channeling at high energies and heavy ion masses, which restricts their ability to capture infrared light efficiently.

Innovation Solution

A low-temperature ion implantation process is performed on CMOS image sensors, cooling them to temperatures below −100° C to enhance ion channeling and achieve deeper photodiode wells, allowing for improved sensitivity and uniform doping profiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If ion implantation is performed at room temperature with existing ion implanters, then the manufacturing process is simple, but the photodiode well depth is limited due to maximum energy constraints and channeling degradation

Engineering Contradiction:
Improvephotodiode well depthVSAvoidmanufacturing process complexity
Core Design Contradiction:
Length of moving objectVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by cooling the wafer to cryogenic temperatures (below -50°C, preferably below -100°C) during ion implantation. This temperature parameter change enhances ion channeling effects, allowing ultra-high energy ions to penetrate deeper into the semiconductor substrate and form photodiode wells exceeding 20 μm in depth, thereby resolving the depth limitation without requiring more complex high-energy implanters

Inventive Principle:
Principle #35Parameter changes

2Length of moving object

If ion energy is increased to achieve deeper photodiode wells, then the well depth increases, but ion channeling degrades at high energies and heavy ion masses

Engineering Contradiction:
Improvephotodiode well depthVSAvoidion channeling effectiveness
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent changes the temperature parameter to cryogenic levels during ion implantation, which preserves and enhances ion channeling effectiveness even at ultra-high ion energies. The low temperature reduces thermal vibrations in the crystal lattice, maintaining the channeling effect that guides ions along crystal planes to achieve depths exceeding 20 μm without the channeling degradation that occurs at room temperature with high-energy ions

Inventive Principle:
Principle #35Parameter changes

3Length of moving object

If cryogenic cooling is applied to enhance ion channeling, then photodiode well depth increases by approximately 2 μm, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvephotodiode well depthVSAvoidmanufacturing ease
Core Design Contradiction:
Length of moving objectVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-cooling the wafer to cryogenic temperatures before performing the ion implantation process. This preparatory cooling step ensures optimal conditions for enhanced ion channeling and deeper photodiode well formation, achieving approximately 2 μm additional depth while allowing the subsequent implantation to proceed with standard equipment and processes

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The low-temperature ion implantation method increases photodiode well depth by approximately 2 μm, enhancing the sensitivity and uniformity of the image sensor's light wavelength response, overcoming the limitations of existing technologies.

Implementation Method 1

cooling the wafer to a temperature less than −50° C.

Methodology Applied
Scientific EffectCryogenic cooling: Cryogenics

Implementation Method 2

performing an ion implant to the photoelectric conversion region to form a photodiode well after cooling the wafer

Methodology Applied
Scientific EffectIon channeling: Ion Beam

Data Source

PatentUS11830739B2Techniques to increase CMOS image sensor well depth by cyrogenic ion channeling of ultra high energy ions
Publication Date: 2023.11.28 APPLIED MATERIALS INC
  • US11830739B2 patent drawing
  • US11830739B2 patent drawing
  • US11830739B2 patent drawing

AI summary

Provided herein are approaches for forming an image sensor with increased well depth due to cryogenic ion channeling of ultra-high energy (UHE) ions. In some embodiments, a method may include providing a wafer of a semiconductor device, the semiconductor device including a photoelectric conversion region, and cooling the wafer to a temperature less than −50° C. The method may further include performing an ion implant to the photoelectric conversion region to form a photodiode well after cooling the wafer.