Carbon Nanotube Thin Film Transistor Flocculation

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Solution Overview

Problem

Current methods for making carbon nanotube-based thin film transistors face challenges with uniform dispersion of carbon nanotubes, low utilization rates, and inflexibility due to aggregation and low concentration, leading to inefficient and rigid devices.

Innovation Solution

A method involving flocculating carbon nanotubes in a solvent, followed by ultrasonic dispersion and air-pumping to form a uniform structure, which is then adhered to a substrate and covered with electrodes and an insulating layer, allowing for improved dispersion, flexibility, and adherence.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If carbon nanotubes are dispersed in organic solvent to form mixture, then carbon nanotube layer can be formed on substrate, but carbon nanotubes aggregate and dispersion uniformity deteriorates

Engineering Contradiction:
Improvedispersion uniformityVSAvoidcarbon nanotube aggregation
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent uses a surfactant as an intermediary substance between carbon nanotubes and organic solvent. The surfactant molecules adsorb onto carbon nanotube surfaces, providing steric or electrostatic repulsion that prevents aggregation. This mediator enables uniform dispersion of carbon nanotubes in the organic solvent without requiring complex agitating steps, directly resolving the contradiction between dispersion uniformity and aggregation tendency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If agitating step is added to achieve uniform dispersion, then dispersion uniformity improves, but carbon nanotubes are wasted and utilization decreases

Engineering Contradiction:
Improvedispersion uniformityVSAvoidcarbon nanotube waste
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

By introducing a surfactant as an intermediary, the patent eliminates the need for intensive agitating steps. The surfactant spontaneously adsorbs onto carbon nanotubes and provides continuous stabilization, allowing uniform dispersion to be achieved through simple mixing rather than prolonged agitation. This prevents carbon nanotube loss that would otherwise occur during mechanical agitating processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If printing method is used to form carbon nanotube layer, then TFT can be manufactured, but carbon nanotube layer becomes inflexible

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidflexibility
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent changes the physical-chemical parameters of the carbon nanotube layer by using a solvent-based dispersion system with surfactant. This allows the carbon nanotubes to be deposited as a flexible colloidal layer rather than a rigid printed structure. The solvent acts as a plasticizer and the surfactant maintains inter-particle spacing, collectively enhancing the flexibility of the carbon nanotube layer while preserving manufacturability through the printing process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a thin film transistor with enhanced carbon nanotube dispersion, reduced waste, improved flexibility, and better adherence to the substrate, addressing the limitations of existing methods by achieving uniformity and flexibility in the carbon nanotube layer.

Implementation Method 1

flocculating the carbon nanotubes to acquire a carbon nanotube structure

Methodology Applied
Scientific EffectFlocculation: Flocculation

Implementation Method 2

ultrasonic dispersion and air-pumping to form a uniform structure

Methodology Applied
Scientific EffectUltrasonic dispersion: Ultrasonic Vibration

Implementation Method 3

ultrasonic dispersion and air-pumping to form a uniform structure

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS8053291B2Method for making thin film transistor comprising flocculating of carbon nanotubes
Publication Date: 2011.11.08 HON HAI PRECISION INDUSTRY CO LTD
  • US8053291B2 patent drawing
  • US8053291B2 patent drawing
  • US8053291B2 patent drawing

AI summary

A method for making a thin film transistor, the method includes the steps of: providing a plurality of carbon nanotubes and an insulating substrate; flocculating the carbon nanotubes to acquire a carbon nanotube structure, applying the carbon nanotube structure on the insulating substrate; forming a source electrode, a drain electrode, and a gate electrode; and covering the carbon nanotube structure with an insulating layer. The source electrode and the drain electrode are connected to the carbon nanotube structure, the gate electrode is electrically insulated from the carbon nanotube structure by the insulating layer.