Co-Host Material Composition for Blue TADF Emitting Layers

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional light emitting devices using exciplex as host material face limitations in selecting thermally activated delayed fluorescent materials and struggle to produce blue light emitting layers due to restricted emission spectrum and energy band gap constraints.

Innovation Solution

A co-host material comprising a first compound and a second compound, specifically designed to satisfy energy level relationships and avoid exciplex formation, is used to create a non-exciplex bipolar composite material, which is mixed with thermally activated delayed fluorescent materials to form a light emitting layer suitable for blue light emitting devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If exciplex is used as host material, then device structure is simplified, but selection of thermally activated delayed fluorescent material is limited and blue light emission is difficult to achieve

Engineering Contradiction:
Improvehost material structureVSAvoidselection of thermally activated delayed fluorescent material
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent uses a composite host material system consisting of a non-exciplex bipolar compound combined with a unipolar compound. This composite approach allows the system to maintain simplified structure while expanding the selection range of thermally activated delayed fluorescent materials and enabling blue light emission, thereby resolving the contradiction between device simplicity and material versatility.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If exciplex host material is used, then device fabrication is simplified, but emission spectrum is restricted and energy band gap constraints prevent blue light emission

Engineering Contradiction:
Improvedevice fabricationVSAvoidemission spectrum range
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent changes the energy level parameters of the host material system by using a non-exciplex bipolar compound with specific HOMO and LUMO levels combined with a unipolar compound. This parameter adjustment expands the emission spectrum range and enables blue light emission while maintaining ease of fabrication through conventional OLED manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional host material is used, then material selection is straightforward, but thermally activated delayed fluorescent material selection is limited

Engineering Contradiction:
Improvematerial selection processVSAvoidthermally activated delayed fluorescent material selection
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The patent segments the host material function into two parts: a non-exciplex bipolar compound that provides the fundamental host properties and a unipolar compound that expands the emission spectrum. This segmentation allows for straightforward material selection based on individual compound properties while achieving versatile thermally activated delayed fluorescent material compatibility and blue light emission.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS12058932B2Co-host material, light emitting layer composition, and light emitting device
Publication Date: 2024.08.06 BOE TECHNOLOGY GROUP CO LTD
  • US12058932B2 patent drawing
  • US12058932B2 patent drawing
  • US12058932B2 patent drawing

AI summary

The present disclosure provides a co-host material, a composition for forming a light emitting layer, and a light emitting device. The co-host material can at least partially solve the difficulty in the limited selection of thermally activated delayed fluorescent materials in the existing light emitting devices, and the difficulty in providing a light emitting layer of a blue light emitting device. The co-host material comprises a first compound and a second compound each having a specific general formula.