CO2-derived Carbon Fiber via Algae and Fischer-Tropsch

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Solution Overview

Problem

Current methods for converting CO2 into usable materials, such as fuels and building materials, are inefficient and costly, and existing carbon fiber production is too energy-intensive to be climate-relevant, while the need for efficient CO2 sequestration and utilization in materials production is urgent to mitigate global warming.

Innovation Solution

A combination of algae-based biomass production and Fischer-Tropsch synthesis processes to produce polyacrylonitrile for carbon fiber production, where CO2 is sequestered from both atmospheric and industrial sources, and converted into acrylonitrile through methanol and propene pathways, optimizing the use of resources and reducing emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional carbon fiber production methods are used, then carbon fibers can be produced, but the energy consumption is too high to be climate-relevant

Engineering Contradiction:
Improvecarbon fiber production efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The invention changes the chemical composition parameters of the precursor material by incorporating recycled carbon content (5-95% by weight) from post-consumer carbon fiber waste, thereby reducing the energy-intensive virgin polymer production while maintaining sufficient mechanical properties for carbon fiber reinforcement applications

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention recovers and reuses carbon fiber waste materials that would otherwise be discarded, transforming them into valuable precursor components for new carbon fiber reinforced plastics, thereby closing the material loop and reducing the energy consumption associated with producing virgin carbon fiber materials

Inventive Principle:
Principle #34Discarding and recovering

2Quantity of substance

If CO2 concentration is increased in the atmosphere, then more CO2 is available for conversion into materials, but global warming increases

Engineering Contradiction:
ImproveCO2 availabilityVSAvoidglobal warming
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The invention converts harmful CO2 emissions from industrial processes and atmospheric sources into valuable carbon-containing precursor materials for carbon fiber production, thereby transforming a greenhouse gas that causes global warming into a useful resource that reduces atmospheric CO2 concentration

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention serves multiple functions simultaneously: it sequesters CO2 from the atmosphere and industrial sources, produces carbon-containing precursors for carbon fiber reinforcement, and reduces greenhouse gas emissions, thereby addressing both material production needs and climate change mitigation in a single integrated process

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Productivity

If algae biomass production is used for CO2 sequestration, then CO2 binding efficiency is high, but the area consumption is relatively large

Engineering Contradiction:
ImproveCO2 binding efficiencyVSAvoidcultivation area
Core Design Contradiction:
ProductivityVSArea of stationary object

Solution Approach 1:

The invention uses algae biomass as an intermediary organism that efficiently captures CO2 from the atmosphere and industrial flue gases, converting it into carbon-containing organic compounds that can be processed into precursor materials for carbon fiber production, thereby bridging the gap between atmospheric CO2 and useful materials

Inventive Principle:
Principle #24Intermediary (Mediator)

4Productivity

If Fischer-Tropsch synthesis is used to produce fuels from CO2, then regenerative fuel production is achieved, but the process complexity and cost increase

Engineering Contradiction:
Improveregenerative fuel productionVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention extracts and isolates carbon-containing compounds from algae biomass through filtration and separation processes, obtaining concentrated carbon sources that can be directly used for precursor production, thereby simplifying the overall process by removing unnecessary intermediate steps compared to full Fischer-Tropsch synthesis pathways

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the efficiency and reduces the cost of carbon fiber production, enabling its widespread adoption in both industrialized and developing regions, promoting climate change mitigation by utilizing CO2 in a regenerative and sustainable manner.

Implementation Method 1

The large-scale production of algae biomass is recommended for economic reasons in technically simple open cultivation basins, which are low-cost industrially scale. An alternative to the extraction of natural CO2 is the power generation, gasification or other energetic utilization of natural algae mass and in particular the sequestration of the CO2 from their flue gases.

Methodology Applied
Scientific EffectPhotosynthesis: Photosynthesis

Implementation Method 2

The state of the art describes methods by which fuels such as biodiesel or kerosene are obtained either via the production of biomass such as, for example, algae growth with sequestered or natural CO2, or that these industry-relevant substances are recovered with the aid of the Fischer-Tropsch synthesis from sequestered CO2 and hydrogen.

Methodology Applied
Scientific EffectFischer-Tropsch synthesis: Catalysis

Implementation Method 3

from which then with the help of carbonisation (through pyrolysis) tensile and especially very rigid carbon fibers are produced, which have a solid state of aggregation over millions of years.

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 4

Both methods also have different starting materials and different valuable by-products, in particular, for example, if the hydrogen obtained by electrolysis releases oxygen as a by-product.

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Data Source

PatentUS11898275B2Carbon fibers which can be produced regeneratively or part-regeneratively from CO2 using combined production methods
Publication Date: 2024.02.13 KUSE KOLJA
  • US11898275B2 patent drawing
  • US11898275B2 patent drawing
  • US11898275B2 patent drawing

AI summary

The invention describes carbon fibers which are produced on the basis of different process chains from CO2. These include routes through natural resources such as algal biomass to produce carbon fiber precursors such as PAN from CO2, as well as the purely synthetic route via the Fischer-Tropsch synthesis, which is also used to make CO2 carbon fiber precursors. In this way, CO2 from anthropogenic origin is to be converted into a solid aggregate state of carbon fiber, which can be disposed of at the end of its life cycle, after being used as highly valuable building material for industry and man, for the construction of buildings and vehicles. These processes produce by-products such as biodiesel and nutrients that generate added value. The production volumes of the resulting substances should be controllable by combining the methods presented here. Some of these processes alone have no long-term climate relevance because of the high costs, but in the initial phase of such a development with the help of carbon dioxide certificates or socio-political necessities they are able to quickly show that carbon fiber building materials can be produced which by themselves are made from CO2 and at least have the quality to be used in the construction sector and for example are feasible to replace steel, in that the paradigm of todays material production being CO2-positive, can be turned into the opposite. If the processes—which have the disadvantage of large-area consumption on the one hand and the of the lack of energy efficiency in the longer term on the other—can be coupled, they have the potential to support each other. By combining the methods, land use and costs can be adjusted to current regional economic performance based on the material paradigm of the future of carbon-negative production of carbon fibers, also depending on the current evolution of CO2 emission allowance prices. The invention has the desired effect in climate policy that high-tech technology transfer can take place into the currently disadvantaged regions of the world, which promotes the economic performance of today's disadvantaged regions and in particular creates the urgently needed jobs in these regions.