Carbon Dioxide Recovery Without Gas Compression

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current carbon-based energy storage systems with a carbon cycle have low energy efficiency due to inefficient synthesis and recovery of carbon dioxide, often requiring gas compression which generates waste heat and reduces efficiency.

Innovation Solution

A system and method for recovering and storing carbon dioxide from carbon-containing compounds without gas compression, utilizing a steam generator, membrane reactor, and condensation device to produce liquid carbon dioxide at high density, with a carbon dioxide-closed permeate mass flow circuit to enhance selectivity and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If gas compression is used to store carbon dioxide at high density, then storage density is improved, but waste heat increases and energy efficiency deteriorates

Engineering Contradiction:
Improvecarbon dioxide storage densityVSAvoidwaste heat from compression
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent utilizes the phase transition of carbon dioxide from gas to liquid state by controlling temperature and pressure conditions. The condensation device cools the carbon dioxide-containing gas to condense it into liquid form, achieving high-density storage without requiring mechanical compression. This phase change approach directly resolves the contradiction by providing dense storage (improving parameter 26) while avoiding compression-induced waste heat (preventing deterioration of parameter 22).

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The system changes the physical parameters of carbon dioxide, specifically temperature and pressure, to achieve liquid-phase storage. By cooling the gas below its critical temperature and maintaining appropriate pressure, the carbon dioxide transitions to a liquid state with higher density. This parameter change strategy enables high-density storage without the energy losses associated with mechanical compression processes.

Inventive Principle:
Principle #35Parameter changes

2Loss of substance

If membrane separation is used to recover carbon dioxide, then recovery completeness is improved, but selectivity may be limited by membrane properties

Engineering Contradiction:
Improvecarbon recovery completenessVSAvoidcarbon dioxide separation selectivity
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent replaces mechanical compression with a membrane-based separation system for carbon dioxide recovery. The membrane reactor uses selective permeation properties to separate carbon dioxide from the gas mixture, achieving high recovery completeness. This substitution of the mechanical compression system with a membrane separation system resolves the contradiction by enabling complete recovery (improving parameter 23) while relying on the membrane's inherent selectivity properties rather than mechanical separation methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention employs porous membrane materials with specific pore structures and surface properties that enable selective passage of carbon dioxide molecules. These porous materials provide the necessary separation selectivity based on molecular size, shape, and interaction properties, allowing high-purity carbon dioxide recovery while maintaining complete separation from other gas components.

Inventive Principle:
Principle #31Porous materials

3Power

If carbon-based energy storage systems are implemented, then energy storage capacity is improved, but energy efficiency deteriorates due to synthesis and recovery losses

Engineering Contradiction:
Improveenergy storage capacityVSAvoidsynthesis and recovery efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The system implements self-service through the carbon cycle, where the carbon dioxide recovered from fuel combustion is directly fed back into the synthesis reactor for producing new fuel. This closed-loop approach eliminates the need for external carbon sources and minimizes energy losses by reusing the carbon component internally. The membrane separation and condensation processes are integrated into the cycle, enabling the system to maintain high energy efficiency while preserving large energy storage capacity.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention establishes continuous operation of the carbon-based energy storage system, where carbon dioxide recovery, condensation, and re-synthesis occur in an uninterrupted cycle. The membrane reactor continuously separates carbon dioxide, the condensation device continuously converts it to liquid form, and the synthesis reactor continuously produces fuel. This continuity eliminates idle periods and maximizes energy efficiency while maintaining full energy storage capacity throughout operation.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables nearly complete recovery and storage of carbon dioxide at high density, reducing waste heat and improving energy efficiency by eliminating gas compression steps, thus enhancing the overall performance of carbon-based energy storage systems.

Implementation Method 1

a steam generator (2) for evaporating water and a substance from the hydrocarbons/ethers/alcohols group

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a membrane reactor (3) for catalytic steam reforming of a substance from the hydrocarbons/ethers/alcohols group and for separating hydrogen gas from the product gas generated by the steam reforming

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 3

a device (6) for condensing out carbon dioxide from a gas mixture containing carbon dioxide

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentEP3448805B1Installation and method for carbon recovery and storage, without the use of gas compression
Publication Date: 2022.01.26 MAIR CHRISTIAN
  • EP3448805B1 patent drawingFigure 1
  • EP3448805B1 patent drawingFigure 2
  • EP3448805B1 patent drawingFigure 3

AI summary

The invention relates to an installation (1) and a method allowing the near total recovery and space-saving storage of carbon in the form of liquid carbon dioxide (19), from a substance (9) of the group consisting of hydrocarbons/ethers/alcohols, without the use of gas compression. To achieve this, a superheated gas (12) at a pressure of over 5.18 bar is generated from the substance (9) of the group consisting of hydrocarbons/ethers/alcohols and water (10), and this gas is delivered, by means of steam reforming and hydrogen liberation, into a retentate mass flow (15) containing carbon dioxide. Liquid carbon dioxide (19) is obtained therefrom by means of condensation, and is stored in a storage tank (7) while the liberated hydrogen is oxidised to provide mechanical and/or electrical as well as thermal energy. The use of membranes with low hydrogen/carbon dioxide permeation selectivity is permitted by forming a permeate mass flow circuit that is closed in respect of carbon dioxide. Operation at low pressures is permitted by the condensation and storage at temperatures below the ambient temperature, for which purpose cold (17) is generated from said thermal energy in a sorption method.