Composite Electrode Layering to Prevent Curling in Solid-State Cells

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Solution Overview

Problem

Solid state batteries face issues with cracking in the solid electrolyte layer during high-pressure pressing, leading to short circuits between the positive and negative electrodes, which is exacerbated by the use of insulating resin layers formed from photocurable liquid compositions that cause curling and peeling.

Innovation Solution

A method of manufacturing electrodes that involves applying a first liquid composition containing a solvent and polymerizable compounds to form an insulating resin layer, followed by applying a second liquid composition with an active material and solvent, and simultaneously removing both solvents to prevent curling, using a porous structure to minimize shrinkage and enhance adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an insulating resin layer is formed from photocurable liquid composition to prevent short circuits during pressing, then electrical insulation is improved, but the layer curls and peels due to shrinkage, worsening structural integrity

Engineering Contradiction:
Improveelectrical insulationVSAvoidstructural integrity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies a porous structure to the insulating resin layer to reduce shrinkage during curing. The porous network allows the resin to maintain volume stability while providing electrical insulation, preventing curling and peeling that would otherwise occur with dense photocurable resin formation.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses composite materials by combining photocurable resin with porous forming agents or fillers. This composite approach maintains the electrical insulation properties of the resin while the porous structure compensates for shrinkage, preventing structural defects during the curing and pressing processes.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If high pressure is applied to achieve high density in solid state batteries, then energy density is improved, but cracking occurs in the solid electrolyte layer, worsening reliability

Engineering Contradiction:
Improveenergy densityVSAvoidelectrolyte integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies beforehand cushioning by creating a compliant interface layer or using flexible binding materials that can absorb pressing pressure. This cushioning effect protects the solid electrolyte layer from cracking while still achieving the desired high density through controlled compression.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The patent employs parameter changes by carefully controlling pressing pressure, temperature, and curing conditions. By optimizing these parameters, the battery achieves high density without exceeding the fracture threshold of the solid electrolyte layer, preventing cracking while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If solvents are removed sequentially from insulating resin layer and electrode composite layer, then each layer can be processed separately, but the process time increases and curling occurs, worsening productivity

Engineering Contradiction:
Improvelayer processing controlVSAvoidmanufacturing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent merges the solvent removal processes for both layers into a single simultaneous operation. By using a common drying or heating step that removes solvents from both the insulating resin layer and electrode composite layer at the same time, the patent reduces total process time and prevents curling that would occur with sequential processing.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent maintains continuity of useful action by performing solvent removal continuously in one step rather than interrupting for separate processing. This continuous action eliminates the time loss between steps and prevents intermediate curing or deformation that would cause curling and reduce productivity.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach prevents electrode curling and short circuits, ensuring high-density electrode formation with improved yield and productivity by maintaining the integrity of the insulating resin layer and electrode composite layer during pressing and lamination processes.

Implementation Method 1

applying a first liquid composition containing a solvent and polymerizable compounds to form an insulating resin layer

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

removing the first solvent to form an insulating resin layer, applying a second liquid composition containing an active material and a second solvent to the substrate, and removing the second solvent composition to form an electrode composite layer

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP4583177A1Method of manufacturing electrode, composite electrode, electrochemical element, and apparatus for manufacturing electrode
Publication Date: 2025.07.09 RICOH CO LTD
  • EP4583177A1 patent drawingFigure 1~2C
  • EP4583177A1 patent drawingFigure 3~4
  • EP4583177A1 patent drawingFigure 5

AI summary

A method of manufacturing an electrode includes applying a first liquid composition containing a first solvent and polymerizable compounds to a substrate, reacting the first liquid composition, removing the first solvent to form an insulating resin layer, applying a second liquid composition containing an active material and a second solvent to the substrate, and removing the second solvent composition to form an electrode composite layer, wherein the removing the first solvent and the removing the second solvent are conducted at the same time.