Composite Polishing Layer Forming Method for CMP Pad

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Solution Overview

Problem

Conventional chemical mechanical polishing pads face challenges in expanding their operating performance range as wafer dimensions shrink, requiring new polishing layer designs that decouple polishing layer stiffness and slurry distribution performance.

Innovation Solution

A method for forming a chemical mechanical polishing pad composite polishing layer using an axial mixing device, where a first polishing layer component with periodic recesses is filled with a combination of poly side and iso side liquid components and pressurized gas, forming a second non-fugitive polymeric phase that solidifies within the recesses, creating a composite structure with enhanced polishing performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional polishing layer designs are used, then manufacturing simplicity is maintained, but polishing performance range is limited

Engineering Contradiction:
Improvepolishing performance rangeVSAvoidpolishing layer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The polishing layer is segmented into multiple discrete components including a porous support layer, a polymeric layer with periodic recesses, and a composite polishing layer. This segmentation allows each layer to be optimized independently for specific functions while maintaining overall manufacturing feasibility through modular construction.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention employs composite materials by combining a polymeric phase with a inorganic filler phase within the composite polishing layer. This composite structure enables simultaneous achievement of enhanced polishing performance and controlled mechanical properties without requiring complete redesign of the entire polishing layer system.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If groove stiffness and fluid flow are optimized separately, then manufacturing simplicity is maintained, but polishing performance balance is limited

Engineering Contradiction:
Improvepolishing performance balanceVSAvoidgroove structure design
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The periodic recesses are strategically positioned and dimensioned to create local variations in stiffness and fluid flow characteristics. By controlling the depth, width, and spacing of individual recesses, the design achieves localized optimization of mechanical properties and slurry distribution without requiring complex overall structural changes.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention utilizes parameter changes by systematically varying the depth, width, pitch, and cross-sectional shape of the periodic recesses. These parameter adjustments enable independent tuning of groove stiffness quotient and groove flow quotient to achieve optimal polishing performance balance for specific application requirements.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If single-phase polishing layers are used, then manufacturing simplicity is maintained, but polishing performance properties are limited

Engineering Contradiction:
Improvepolishing performance propertiesVSAvoidlayer composition
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The composite polishing layer combines organic polymeric phases with inorganic filler phases, enabling simultaneous achievement of enhanced polishing performance properties and controlled mechanical characteristics. This composite approach expands the available performance property range without requiring complete system redesign.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polishing layer is divided into functionally distinct phases including continuous polymeric matrix and dispersed inorganic filler particles. This phase segmentation allows each component to contribute specific performance properties while maintaining manufacturing feasibility through established composite material processing techniques.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method breaks the mold of established Groove Stiffness Quotient and Groove Flow Quotient parameters, expanding the range of polishing performance properties and achieving unobtainable balances of polishing performance, resulting in improved planarization and substrate polishing capabilities.

Implementation Method 1

wherein the poly side (P) liquid component, the iso side (I) liquid component and the pressurized gas are intermixed within the internal cylindrical chamber to form a combination

Methodology Applied
Scientific EffectTurbulence: Turbulence

Implementation Method 2

wherein an inlet velocity into the internal cylindrical chamber of the pressurized gas is 90 to 600 m/s; discharging the combination from the open end of the internal cylindrical chamber toward the polishing side of the first polishing layer component at a velocity of 10 to 300 msec

Methodology Applied
Scientific EffectKinetic energy conversion:

Implementation Method 3

providing a poly side (P) liquid component, comprising at least one of a (P) side polyol, a (P) side polyamine and a (P) side alcohol amine; providing an iso side (I) liquid component, comprising at least one polyfunctional isocyanate

Methodology Applied
Scientific EffectPolymerization reaction:

Implementation Method 4

allowing the combination to solidify as a second polishing layer component in the plurality of periodic recesses to form a composite structure

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS10011002B2Method of making composite polishing layer for chemical mechanical polishing pad
Publication Date: 2018.07.03 DUPONT ELECTRONIC MATERIALS HLDG INC
  • US10011002B2 patent drawing
  • US10011002B2 patent drawing
  • US10011002B2 patent drawing

AI summary

A method of forming a chemical mechanical polishing pad composite polishing layer is provided, including: providing a first polishing layer component of a first continuous non-fugitive polymeric phase having a plurality of periodic recesses; discharging a combination toward the first polishing layer component at a velocity of 10 to 300 msec, filling the plurality of periodic recesses with the combination; allowing the combination to solidify in the plurality of periodic recesses forming a second non-fugitive polymeric phase giving a composite structure; and, deriving the chemical mechanical polishing pad composite polishing layer from the composite structure, wherein the chemical mechanical polishing pad composite polishing layer has a polishing surface on the polishing side of the first polishing layer component; and wherein the polishing surface is adapted for polishing a substrate.