Conductive Adhesive Composition With Delayed Curing for Filler Bonding

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Solution Overview

Problem

Conductive adhesives used in electronics assembly often have insufficient adhesive strength due to the thermosetting resin curing too quickly, hindering the bonding of conductive fillers, and there is a need for lead-free alternatives to solder.

Innovation Solution

A conductive adhesive composition featuring a bismaleimide resin with a reaction initiation temperature of 180°C or higher, combined with a filler and catalyst, to ensure smooth bonding of fillers and substrates, along with a flux to facilitate melting and bonding, and a polymer component for enhanced film formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a thermosetting resin is used in conductive adhesive, then adhesive strength is improved, but curing occurs too quickly which hinders filler bonding

Engineering Contradiction:
Improveadhesive strengthVSAvoidcuring time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent changes the key parameter of reaction initiation temperature to 180°C or higher, which delays the onset of curing compared to conventional resins. This parameter modification allows the adhesive to remain workable longer during application while still achieving strong bonding, resolving the contradiction between adhesive strength and curing speed.

Inventive Principle:
Principle #35Parameter changes

2Strength

If curing of thermosetting resin progresses quickly, then adhesive strength is improved, but bonding of conductive filler is hindered

Engineering Contradiction:
Improveadhesive strengthVSAvoidfiller bonding
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

By setting the reaction initiation temperature at 180°C or higher, the patent creates a temporal window where filler bonding can occur before resin curing begins. This parameter change ensures that conductive particles can properly bond to substrates and to each other without being hindered by premature resin crosslinking, thereby maintaining both adhesive strength and filler bonding reliability.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If lead-free solder is used, then environmental harm is reduced, but adhesive strength is insufficient

Engineering Contradiction:
Improveenvironmental harmVSAvoidadhesive strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent employs a composite material system combining a bismaleimide thermosetting resin with specific conductive fillers (such as silver particles) and curing agents. This composite formulation achieves both environmental compatibility by eliminating lead and superior adhesive strength through the synergistic interaction of resin, filler, and curing agent, where the high reaction initiation temperature ensures proper filler bonding.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides superior adhesive properties and conductivity without using harmful substances, ensuring strong bonding between fillers and substrates, even at higher temperatures, making it effective for low-melting point solders.

Implementation Method 1

a thermosetting resin, wherein the thermosetting resin is a bismaleimide resin... and at least one catalyst or curing agent, wherein the reaction initiation temperature for the thermosetting resin and the at least one catalyst or curing agent is 180°C or higher

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

the bonding of the filler may be hindered if the curing of the thermosetting resin progress more quickly than the melting and bonding of the conductive filler

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentEP3187560B1Electrically conductive adhesive composition
Publication Date: 2024.01.17 FURUKAWA ELECTRIC CO LTD
  • EP3187560B1 patent drawingFigure 1~2
  • EP3187560B1 patent drawing
  • EP3187560B1 patent drawing

AI summary

A conductive adhesive that does not contain toxic substances such as solder (lead) and shows excellent adhesiveness is provided. Specifically, it is a conductive adhesive composition, which comprises (A) a thermosetting resin; (C) a filler that contains a metal element; and (D) at least one catalyst or curing agent, wherein the reaction initiation temperature for the (A) thermosetting resin and the (D) at least one catalyst or curing agent is 180°C or higher. More preferably, the reaction initiation temperature is 200°C or higher. More preferably, it is a conductive adhesive composition that further comprises (B) a flux and (E) a polymer component.