Conductive Layer Formation in Composite Resin Particles

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Solution Overview

Problem

Existing conductive resin materials require high concentrations of expensive conductive materials, which increase production costs and can adversely affect the resin's workability and strength, while low concentrations result in insufficient conductivity.

Innovation Solution

A composite resin material particle is created by dispersively mixing conductive nano-materials into the surface of resin material particles using ultrasonic waves in a subcritical or supercritical carbon dioxide environment, forming a conductive layer that maintains continuity during molding, reducing the need for high material concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a large amount of conductive material is added to achieve sufficient conductivity, then the conductivity is improved, but the molding property and strength of the resin is lowered

Engineering Contradiction:
ImproveconductivityVSAvoidresin strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The conductive material is concentrated in the surface layer of the resin particle rather than being uniformly distributed throughout the bulk. This creates a local conductive network at the surface while preserving the bulk resin properties, thereby achieving sufficient conductivity without compromising overall resin strength and molding properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention transitions from three-dimensional uniform distribution of conductive material to a two-dimensional surface-layer distribution. By forming a conductive layer only in the surface region of resin particles, the patent achieves conductivity enhancement with minimal conductive material dosage, avoiding the strength reduction that would result from bulk incorporation of large amounts of conductive filler.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Quantity of substance

If the dose of expensive conductive material is reduced to lower production cost, then the cost is improved, but the conductivity becomes insufficient

Engineering Contradiction:
Improveconductive material dosageVSAvoidconductivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

By concentrating conductive material in the surface layer rather than distributing it uniformly throughout the resin particle, the invention achieves efficient use of conductive material. The surface layer forms effective conductive pathways while minimizing the total amount of expensive conductive material required, thus maintaining conductivity at lower dosages.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention creates a composite structure with distinct functional zones: a conductive surface layer and a non-conductive bulk resin. This composite architecture allows the conductive material to be strategically positioned where it is most needed for electrical performance, optimizing the balance between conductivity and material cost.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If carbon black is used as conductive material to avoid high cost, then the cost is reduced, but the conductivity of the material itself is low requiring large dosage

Engineering Contradiction:
Improveconductive material dosageVSAvoidconductivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The invention concentrates carbon black in the surface layer of resin particles, creating a high-density conductive network at the surface where it is most effective. This localized concentration compensates for the inherently low conductivity of carbon black, achieving sufficient overall conductivity with a smaller total dosage than would be required for uniform distribution.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for the production of highly conductive molding products with reduced conductive material usage, maintaining conductivity and strength while lowering production costs.

Implementation Method 1

dispersively mixing conductive nano-materials into the surface of resin material particles using ultrasonic waves

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Implementation Method 2

in a subcritical or supercritical carbon dioxide environment

Methodology Applied
Scientific EffectSupercritical fluid extraction: Supercritical Fluid Extraction

Implementation Method 3

the conductive material is kept from being freed due to the viscosity of the melted resin material liquid

Methodology Applied
Scientific EffectViscosity:

Implementation Method 4

since carbon nano-materials are hydrophobic, they have a high affinity with resins

Methodology Applied
Scientific EffectHydrophobe: Hydrophobe

Data Source

PatentUS10435519B2Composite resinous material particles and process for producing same
Publication Date: 2019.10.08 NIPPON SANSO CORP
  • US10435519B2 patent drawing
  • US10435519B2 patent drawing
  • US10435519B2 patent drawing

AI summary

A composite resin material particle of the present invention includes: a resin material particle that is a material for producing a resin molding product; and a conductive nano-material, wherein a dispersion mixing layer, which is obtained by dispersedly mixing the conductive nano-material from the surface to the inside of the resin material particle, is formed over all of the surface or at least a part of the surface of the resin material particle, the conductive nano-material is dispersedly mixed within a resin material of the resin material particle in the dispersion mixing layer, and the whole of the dispersion mixing layer forms a conductive layer.