Confocal XRF and CT Integration for 3D Ore Analysis

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Solution Overview

Problem

Current methods for analyzing tailings samples, such as the Mineral Liberation Analyzer (MLA), face challenges including low statistical data sets, limited 3-D information, overestimation of mineral recovery, destructive sample preparation, and lengthy analysis times, which hinder efficient extraction of precious metals like platinum.

Innovation Solution

Integration of high-resolution x-ray computed tomography (CT) with confocal x-ray fluorescence (XRF) systems, enabling 3-D imaging and elemental composition analysis, allowing for non-destructive sampling and rapid data collection with improved spatial resolution and sensitivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of information

If traditional 2-D MLA analysis is used, then sample preparation is simpler, but 3-D contextual information is lost and mineral recovery is overestimated

Engineering Contradiction:
Improve3-D contextual informationVSAvoidsystem complexity
Core Design Contradiction:
Loss of informationVSDevice complexity

Solution Approach 1:

The patent transitions from 2-D surface analysis to 3-D volumetric analysis by integrating x-ray CT scanning capability. The system acquires projection data at multiple angles and reconstructs three-dimensional tomographic volumes, enabling analysis of mineral grains in their true 3-D context without destructive sample preparation, thereby recovering lost spatial information while maintaining operational feasibility

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent merges two analytical modalities - x-ray CT for 3-D structural imaging and confocal XRF for elemental composition analysis - into a single integrated system. The CT subsystem provides spatial context and the XRF subsystem provides chemical identification, with both systems sharing common x-ray source and detection infrastructure, reducing overall system complexity while comprehensively addressing the information loss problem

Inventive Principle:
Principle #5Merging (Combining)

2Measurement precision

If multiple tailing samples are measured to increase statistical data, then data representativeness improves, but analysis time increases significantly

Engineering Contradiction:
Improvestatistical significanceVSAvoidanalysis time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent segments the analysis process into two phases: first, rapid 3-D localization of all mineral grains using x-ray CT scanning of a single representative sample; second, targeted confocal XRF analysis only of grains identified as containing precious metals. This segmentation eliminates the need to analyze multiple bulk samples while maintaining statistical significance, reducing analysis time from days to hours

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system performs preliminary 3-D imaging and grain localization using x-ray CT before conducting the more time-consuming elemental analysis. By pre-identifying which grains contain precious metals through density-based segmentation of the CT data, the system avoids unnecessary XRF measurements on non-target grains, significantly reducing total analysis time while preserving measurement precision

Inventive Principle:
Principle #10Preliminary action

3Loss of information

If confocal XRF analyzes all points in 3-D volume, then complete elemental mapping is achieved, but measurement time becomes prohibitively long

Engineering Contradiction:
Improveelemental composition dataVSAvoidmeasurement throughput
Core Design Contradiction:
Loss of informationVSProductivity

Solution Approach 1:

The patent applies local quality by directing confocal XRF analysis only to specific regions of interest identified in the 3-D CT volume - namely, grains with density characteristics indicating precious metal content. Rather than uniformly analyzing the entire 3-D volume, the system concentrates analytical resources on locally relevant regions, achieving complete elemental mapping where needed while maintaining high measurement throughput

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The system performs partial analysis by selecting a limited subset of measurement points within the 3-D volume for confocal XRF analysis. Using CT-derived density information to identify approximately 10-20 candidate grains per sample, the system analyzes only these partial regions rather than the excessive number of points required for complete volumetric mapping, achieving sufficient elemental composition data with dramatically reduced measurement time

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This combination provides statistically relevant 3-D data for precise localization and identification of precious metal grains, optimizing extraction yields and reducing analysis time, while avoiding the limitations of traditional 2-D methods.

Implementation Method 1

High-resolution x-ray computed tomography (CT) is a widespread imaging modality

Methodology Applied
Scientific EffectX-ray: X-Ray

Implementation Method 2

The tomographic volumes are generated from the projection data using software reconstruction algorithms based on back-projection and other image processing techniques

Methodology Applied
Scientific EffectBack-projection:

Implementation Method 3

confocal x-ray fluorescence (XRF) systems, enabling 3-D imaging and elemental composition analysis

Methodology Applied
Scientific EffectX-ray fluorescence: Fluorescence

Data Source

PatentEP2893331B1Combined confocal x-ray fluorescence and x-ray computerised tomographic system and method
Publication Date: 2020.01.15 CARL ZEISS X-RAY MICROSCOPY INC
  • EP2893331B1 patent drawingFigure 1A
  • EP2893331B1 patent drawingFigure 1B
  • EP2893331B1 patent drawingFigure 2

AI summary

A correlative evaluation of a sample using an x-ray computed tomography (CT) x-ray fluorescence (XRF) system and the method for analyzing a sample using x-ray CT and XRF is disclosed. The CT/XRF system includes an x-ray CT subsystem for acquisition of volume information and a confocal XRF subsystem for acquisition of elemental composition information. The CT/XRF system also includes a controller for managing the acquisitions by the x-ray CT subsystem and confocal XRF subsystem. Combining sub-micrometer spatial resolution 3-D imaging with elemental composition analysis in 3-D with ppm level sensitivity is important to elemental identification of precious metal grains in crushed and ground ores and floatation tailings in the mining industry.