Continuous Plasma Etching for Smooth Semiconductor Trench Profiles

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Solution Overview

Problem

The Bosch process for anisotropically etching semiconductor wafers results in uneven surfaces due to its cyclic nature, leading to scalloping and side wall roughening, and is sensitive to temperature and parameter changes, making it difficult to achieve accurate and reproducible deep etch features.

Innovation Solution

A continuous plasma etching method using a mixture of halogen gases, halocarbons, and nitrogen compounds to selectively remove passivation material from the closed end of etch features while maintaining it on the sidewalls, preventing undercutting and promoting smooth, anisotropic profiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the Bosch process uses cyclic etch and deposition steps to etch deep features, then the anisotropic etching is achieved, but uneven surfaces with scalloping and side wall roughening occur

Engineering Contradiction:
Improveetch feature profile accuracyVSAvoidside wall smoothness
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The patent applies a continuous plasma etching process instead of cyclic steps, maintaining constant passivation material deposition on sidewalls while removing it from the base. This continuous action eliminates the scalloping effect caused by repeated deposition and removal cycles, producing smooth sidewalls while maintaining anisotropic etching.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent creates different conditions at different locations within the etch feature: passivation material is continuously removed from the base (closed end) while being maintained on the sidewalls. This spatial differentiation allows selective etching at the base while protecting sidewalls, achieving both precision and smoothness.

Inventive Principle:
Principle #3Local quality

2Reliability

If the Bosch process uses cyclic deposition steps to maintain anisotropic etching, then sidewall protection is improved, but the process becomes sensitive to temperature and parameter changes

Engineering Contradiction:
Improvemask selectivityVSAvoidprocess parameter stability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The continuous plasma process maintains constant passivation material deposition, eliminating the sensitivity to timing and parameter changes inherent in cyclic processes. The continuous nature provides inherent stability against temperature and parameter fluctuations while maintaining reliable sidewall protection.

Inventive Principle:
Principle #20Continuity of useful action

3Duration of action of stationary object

If lower wafer temperatures are used to improve mask life, then mask durability increases, but excessive polymer growth causes grass formation at the base

Engineering Contradiction:
Improvemask lifeVSAvoidgrass formation
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent creates local differences in passivation material behavior: at lower temperatures, polymer deposits heavily on the base (causing grass formation) but this is continuously removed by the plasma. On sidewalls, the polymer is maintained at controlled thickness. This local differentiation allows low temperature operation with extended mask life without grass formation problems.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent converts the harmful grass formation effect into a beneficial one: the excessive polymer deposition at the base is continuously removed by the plasma, and this same plasma maintains sidewall protection. The continuous process transforms what would be a defect into a self-correcting mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces side wall roughness and scalloping, improves control over the etching process, and allows for deeper etch features with smoother profiles, enhancing the manufacturability of silicon trench etched wafers and enabling higher integration levels in ASIC circuitry.

Implementation Method 1

forming a plasma of the etching mixture in the environment for etching the wafer

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

Ions entering the dark space sheath of the etching plasma are accelerated by the sheath field and impact onto the substrate at an angle substantially normal to the wafer plane increasing the anisotropic etching

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Implementation Method 3

at least one passivation component for depositing passivation material on the wafer

Methodology Applied
Scientific EffectPlasma-enhanced chemical vapor deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 4

at least one passivation material removal component for removing passivation material deposited on a wall of a closed end of an etch feature of the wafer

Methodology Applied
Scientific EffectPlasma chemical reactions: Plasma

Data Source

PatentUS8759214B2Method of etching a semiconductor wafer
Publication Date: 2014.06.24 RADIATION WATCH LTD
  • US8759214B2 patent drawing
  • US8759214B2 patent drawing
  • US8759214B2 patent drawing

AI summary

A method for anisotropically plasma etching a semiconductor wafer is disclosed. The method comprises supporting a wafer in an environment operative to form a plasma, such as a plasma reactor, and providing an etching mixture to the environment. The etching mixture comprises at least one etch component, at least one passivation component, and at least one passivation material removal component.