Processes and systems for controlling cooling fluid

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Solution Overview

Problem

Existing ionic liquid alkylation processes face challenges in controlling temperature without vaporization, as the high viscosity and potential fouling of ionic liquids impact heat transfer, and conjunct polymers produced in these reactions further complicate heat management, necessitating an efficient and flexible heat removal system that can operate effectively across variable reaction temperatures and heat duties.

Innovation Solution

A cooling fluid circulation system and process that utilizes a chiller loop to control the temperature of the cooling fluid within a specific range, allowing for efficient heat exchange through strategically placed heat exchangers, minimizing fouling and maintaining reactants and products in a liquid state, with the ability to adjust fluid flow based on temperature measurements to ensure optimal cooling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If heat exchange is used to control temperature in ionic liquid alkylation, then temperature control is improved, but heat transfer efficiency deteriorates due to high viscosity and fouling of ionic liquids

Engineering Contradiction:
Improvetemperature controlVSAvoidheat transfer efficiency
Core Design Contradiction:
TemperatureVSLoss of energy

Solution Approach 1:

The reactor is divided into multiple reaction zones with interspersed heat exchange zones. This segmentation allows for distributed heat removal throughout the reaction process, preventing localized overheating and reducing the overall thermal load on any single heat exchanger, thereby maintaining better heat transfer efficiency despite ionic liquid viscosity and fouling tendencies.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A cooling fluid circulation system is introduced as an intermediary medium to transfer heat from the ionic liquid reaction mixture. The cooling fluid (separate from the ionic liquid) circulates through heat exchangers, absorbing heat without direct contact with the viscous ionic liquid, thus overcoming the heat transfer efficiency problem while maintaining effective temperature control.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Temperature

If vaporization is used to control temperature in ionic liquid alkylation, then temperature control is achieved, but operational control and reactant dispersion deteriorate

Engineering Contradiction:
Improvetemperature controlVSAvoidoperational control
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

Instead of changing the phase of the reactants (vaporization), the system maintains all reactants and products in the liquid phase and controls temperature by adjusting cooling fluid flow rates and temperatures. This parameter change from phase transition-based control to fluid circulation-based control preserves operational simplicity and reactant dispersion while achieving temperature control.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If cooling fluid flow is increased to improve heat removal, then heat removal efficiency is improved, but system complexity and energy consumption increase

Engineering Contradiction:
Improveheat removal efficiencyVSAvoidsystem complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The cooling fluid flow rate and temperature are made dynamically adjustable rather than fixed. The system can adapt the cooling intensity to match the actual heat generation rate of the reaction, providing optimal heat removal efficiency while avoiding excessive energy consumption and system complexity through flexible, responsive control.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively controls temperature in ionic liquid alkylation processes, maintaining product quality and yield by providing a flexible and efficient heat removal system that operates independently of ambient conditions, reducing the impact of temperature fluctuations on alkylate product quality.

Implementation Method 1

heat exchange through strategically placed heat exchangers

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

efficient heat exchange

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 3

utilizes a chiller loop to control the temperature of the cooling fluid within a specific range

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 4

The alkylation reaction is highly exothermic

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentEP3310471B1Processes and systems for controlling cooling fluid
Publication Date: 2022.12.07 UOP LLC
  • EP3310471B1 patent drawingFigure 1
  • EP3310471B1 patent drawingFigure 2
  • EP3310471B1 patent drawingFigure 3

AI summary

Processes for controlling the rate and temperature of cooling fluid through a heat exchange zone in, for example, an alkylation reactor using an ionic liquid catalyst. A cooling fluid system may be used to provide the cooling fluid which includes a chiller and a reservoir. The cooling fluid may pass from the reservoir through the heat exchange zone. A bypass line may be used to pass a portion of the cooling fluid around the heat exchange zone. The amount of cooling fluid may be adjusted, with a valve, based upon the temperature of the cooled process fluid flowing out of the heat exchange zone. Some of the cooling fluid from the chiller may be circulated back to the chiller in a chiller loop.