Copper Bump Joint Crack Resistance via Palladium Intermediary

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Solution Overview

Problem

Lead-free solder joints in semiconductor packaging are prone to cracking due to thermal expansion mismatch and the brittleness of materials like SnAg and SnAgCu, which fail reliability tests such as thermal cycles, especially when copper bumps are used.

Innovation Solution

Incorporating a palladium layer between the copper bumps and bond pads, allowing palladium to diffuse into the solder and form intermetallic compounds that enhance crack resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lead-free solder materials (SnAg, SnAgCu) are used to replace lead-containing solders, then environmental compliance is improved, but crack resistance deteriorates

Engineering Contradiction:
Improvecrack resistanceVSAvoidbrittleness
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A palladium layer is introduced as an intermediary between the copper bump and the lead-free solder joint. This palladium layer acts as a mediator that reduces the harmful interaction between the rigid copper bump and the brittle solder material, thereby improving crack resistance while maintaining the benefits of lead-free soldering.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If copper bumps are used in semiconductor chips, then electrical conductivity is improved, but stress on solder joints increases leading to cracking

Engineering Contradiction:
Improveelectrical conductivityVSAvoidthermal stress
Core Design Contradiction:
ReliabilityVSStress or pressure

Solution Approach 1:

The palladium layer serves as a stress-buffering intermediary between the rigid copper bump and the solder joint. It reduces the transmission of thermal expansion stress from the copper bump to the brittle solder, thereby decreasing cracking while preserving the high electrical conductivity benefits of copper bumps.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If rigid copper bumps are used, then electrical performance is improved, but crack resistance of adjacent solder deteriorates

Engineering Contradiction:
Improveelectrical performanceVSAvoidcrack resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The palladium layer is positioned between the rigid copper bump and the solder joint to act as a mechanical intermediary. It cushions the rigid copper structure's impact on the brittle solder, improving crack resistance while allowing the copper bump to maintain its superior electrical performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Adaptability or versatility

If CTE mismatch between materials is present, then manufacturing flexibility is improved, but thermal stress increases causing solder cracking

Engineering Contradiction:
Improvematerial selection flexibilityVSAvoidthermal expansion stress
Core Design Contradiction:
Adaptability or versatilityVSStress or pressure

Solution Approach 1:

The palladium layer acts as a CTE-matching intermediary between materials with different thermal expansion coefficients (copper, dielectric, package substrate). It reduces the stress concentration caused by CTE mismatch during thermal cycling, thereby preventing solder cracking while allowing continued use of diverse materials for manufacturing flexibility.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces crack lengths in solder joints from 70-80 μm to less than 20 μm, improving the reliability of lead-free solder joints under thermal stress.

Implementation Method 1

allowing palladium to diffuse into the solder and form intermetallic compounds that enhance crack resistance

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS9607936B2Copper bump joint structures with improved crack resistance
Publication Date: 2017.03.28 PARABELLUM STRATEGIC OPPORTUNITIES FUND LLC
  • US9607936B2 patent drawing
  • US9607936B2 patent drawing
  • US9607936B2 patent drawing

AI summary

An integrated circuit structure includes a first work piece and a second work piece. The first work piece includes a semiconductor substrate, and a copper bump over the semiconductor substrate. The second work piece includes a bond pad. A solder is between and adjoining the first work piece and the second work piece, wherein the solder electrically connects the copper bump to the bond pad. The solder includes palladium.