Copper-Ceramic Composite Grain Size Gradient

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Solution Overview

Problem

In high-power electronics, metal-ceramic composites face challenges with thermal shock resistance and wire bonding due to differences in thermal expansion coefficients between ceramic substrates and metal coatings, leading to potential detachment under temperature fluctuations.

Innovation Solution

A copper-ceramic composite with a copper or copper alloy coating having grain sizes between 10 μm to 300 μm, optimized grain size distribution, and shape factors to enhance adhesion and thermal shock resistance, allowing for strong wire bonding and improved mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the metal coating is firmly bonded to the ceramic substrate, then adhesion strength is improved, but wire bonding becomes difficult due to material incompatibility

Engineering Contradiction:
Improveadhesion strengthVSAvoidwire bonding
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies different grain sizes in different regions of the copper coating. The central region has finer grains (5-20 μm) for strong adhesion to ceramic, while the peripheral region has coarser grains (20-50 μm) that are more suitable for wire bonding. This local differentiation resolves the contradiction between adhesion strength and wire bonding compatibility.

Inventive Principle:
Principle #3Local quality

2Strength

If the copper grain size is reduced to improve adhesion, then adhesive strength is improved, but thermal shock resistance deteriorates

Engineering Contradiction:
Improveadhesive strengthVSAvoidthermal shock resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent implements a gradient grain size distribution where the central region has finer grains (5-20 μm) for strong adhesion, while the peripheral region has coarser grains (20-50 μm) for better thermal shock resistance. This spatial variation in grain size allows both adhesion strength and thermal shock resistance to be optimized simultaneously.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the grain size parameter across the copper coating thickness and lateral dimensions. By controlling grain size to vary from 5-20 μm in the center to 20-50 μm at the periphery, the material properties are optimized for different functional requirements: adhesion in the center and thermal shock resistance at the edges.

Inventive Principle:
Principle #35Parameter changes

3Strength

If uniform fine grain structure is used throughout the copper coating, then adhesion to ceramic is improved, but thermal expansion mismatch stresses increase during temperature cycling

Engineering Contradiction:
Improveadhesion to ceramicVSAvoidthermal expansion stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The patent creates a non-uniform grain structure with finer grains (5-20 μm) in the central region for strong adhesion and coarser grains (20-50 μm) in the peripheral region. This local differentiation allows the peripheral area to better accommodate thermal expansion stresses while maintaining strong central adhesion to the ceramic substrate.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite exhibits improved thermal shock resistance, increased wire bonding strength, and enhanced adhesive strength, maintaining bonding integrity under prolonged temperature changes.

Implementation Method 1

the copper or the copper alloy has grain sizes in the range from 10 μm to 300 μm

Methodology Applied
Scientific EffectGrain growth: Crystallisation

Implementation Method 2

This layer reacts with the surface of the ceramic substrate, so that ceramic and metal can be firmly joined to one another

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

oxygen reduces the melting point of the copper from 1083° C. to the eutectic melting point of 1065° C. A thin eutectic melt layer is formed by the oxidation of copper foils

Methodology Applied
Scientific EffectEutectic melting: Melting

Implementation Method 4

Ceramic circuit boards are of particular interest in the field of high-power electronics because of their high thermal conductivity

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS11021406B2Copper-ceramic composite
Publication Date: 2021.06.01 HERAEUS ELECTRONICS GMBH & CO KG
  • US11021406B2 patent drawing
  • US11021406B2 patent drawing
  • US11021406B2 patent drawing

AI summary

The invention relates to a copper-ceramic composite comprising: a ceramic substrate; and a copper or copper alloy coating on the ceramic substrate, the copper or copper alloy having grain sizes of 10 μm to 300 μm.