Copper Barrier CMP Slurry With PIB Beads for Pad Life Extension

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Solution Overview

Problem

Conventional chemical-mechanical planarization (CMP) technologies face challenges with frequent pad and conditioner replacements, leading to waste generation, variable contact area distributions, and reduced polishing pad and conditioner lifetimes, affecting process stability and wafer topography.

Innovation Solution

The introduction of pad-in-a-bottle (PIB) technology using Cu barrier CMP slurries with micron-sized polyurethane beads and a silicone-containing dispersing agent, combined with fractional conditioning, to enhance polishing pad and conditioner lifetimes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional CMP is used with frequent pad replacement, then pad surface renewal is achieved, but waste generation increases and pad lifetime decreases

Engineering Contradiction:
Improveprocess stabilityVSAvoidwaste generation
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The polishing slurry contains polyurethane beads that self-renew the pad surface through mechanical action during polishing, eliminating the need for external diamond disk conditioners. The beads continuously regenerate pad asperities by mechanically exfoliating the pad surface, allowing the system to maintain its own polishing capability without external intervention.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The polyurethane beads in the slurry recover and reuse pad material by mechanically exfoliating and redistributing pad particles during polishing. This process recovers potentially useful pad material that would otherwise be wasted, converting it into active polishing components that continue to contribute to the polishing action.

Inventive Principle:
Principle #34Discarding and recovering

2Duration of action of moving object

If diamond disk conditioning is used to renew pad surface, then pad asperities are regenerated, but conditioning disk life decreases

Engineering Contradiction:
Improvepad renewal capabilityVSAvoidconditioning disk life
Core Design Contradiction:
Duration of action of moving objectVSDuration of action of stationary object

Solution Approach 1:

The polishing slurry contains polyurethane beads that self-renew the pad surface through mechanical action during polishing, eliminating the need for external diamond disk conditioners. The beads continuously regenerate pad asperities by mechanically exfoliating the pad surface, allowing the system to maintain its own polishing capability without external intervention.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention extracts the conditioning function from the diamond disk and transfers it to polyurethane beads suspended in the slurry. By removing the harmful diamond disk from the system and replacing it with benign polyurethane beads, the patent eliminates the wear and degradation associated with diamond disk usage while maintaining the essential pad renewal capability.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If full pad conditioning is applied, then pad surface is renewed, but pad and conditioner lifetime are reduced

Engineering Contradiction:
Improvepad surface qualityVSAvoidpad life
Core Design Contradiction:
Manufacturing precisionVSDuration of action of moving object

Solution Approach 1:

The polyurethane beads in the slurry apply continuous partial conditioning action during normal polishing operations. Rather than requiring intensive periodic conditioning, the beads provide ongoing gentle surface renewal that maintains pad quality without the excessive mechanical stress that would shorten pad and conditioner life.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The conditioning action is made continuous through the presence of polyurethane beads in the polishing slurry. As polishing proceeds, the beads continuously interact with the pad surface, providing ongoing renewal and maintenance of pad asperities without interruption or the need for separate conditioning cycles.

Inventive Principle:
Principle #20Continuity of useful action

4Manufacturing precision

If frequent pad replacement is performed, then contact area distribution is controlled, but productivity decreases

Engineering Contradiction:
Improvecontact area distributionVSAvoidprocess efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The polishing slurry contains polyurethane beads that self-renew the pad surface through mechanical action during polishing, eliminating the need for external diamond disk conditioners. The beads continuously regenerate pad asperities by mechanically exfoliating the pad surface, allowing the system to maintain its own polishing capability without external intervention.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The PIB technology significantly extends the life of polishing pads and conditioners by 4 to 2 times compared to traditional methods, reducing waste and environmental impact while maintaining stable removal rates, thus improving process efficiency and cost-effectiveness.

Implementation Method 1

a silicone-containing dispersing agent

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

asperities on a polyurethane (PU) pad are irreversibly deformed due to wafer contact and are also abraded by composition particles

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 3

asperities on a polyurethane (PU) pad are irreversibly deformed due to wafer contact

Methodology Applied
Scientific EffectMechanical deformation: Deformation

Data Source

PatentUS20240352279A1Pad-in-a-bottle (PIB) technology for copper barrier slurries
Publication Date: 2024.10.24 VERSUM MATERIALS US LLC

AI summary

A novel pad-in-a-bottle (PIB) technology for advanced chemical-mechanical planarization (CMP) copper barrier CMP compositions, systems and processes has been disclosed for use with polyurethane-based polishing pads having a plurality of asperities. The CMP composition comprises abrasives, polyurethane beads, and surfactant. The polishing pad lifetime increasing is achieved using PIB-type Cu barrier CMP polishing composition.