Copper Oxide Ink Composition for Stable Low-Resistance Conductive Films

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Solution Overview

Problem

Existing methods for manufacturing conductive substrates using metal inks or pastes face challenges such as high resistivity and instability over time, particularly due to oxidation of metal particles like copper.

Innovation Solution

A copper oxide ink is developed comprising copper oxide, a dispersant, and a reducing agent, with specific content ratios to enhance dispersion stability, storage stability, and the formation of conductive films with low resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If copper ultrafine particles are used to form conductive films, then conductivity is improved, but oxidation occurs readily leading to high resistivity over time

Engineering Contradiction:
Improveconductivity stabilityVSAvoidoxidation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses copper oxide particles as an intermediary substance between copper metal and the oxidizing environment. The copper oxide layer acts as a protective barrier that prevents further oxidation of the conductive copper particles, while still allowing the formation of conductive networks through sintering and particle aggregation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates an inert environment by incorporating antioxidant agents and controlling the atmosphere during storage and processing. This prevents oxygen from reaching the copper particles, thereby maintaining low resistivity over time without requiring vacuum or inert gas packaging.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Reliability

If copper oxide is reduced to copper by heat treatment, then conductivity is improved, but sintering is hindered by antioxidation treatment

Engineering Contradiction:
ImproveconductivityVSAvoidsintering process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the particle size of copper oxide to ultrafine ranges (1-100 nm), which fundamentally changes the sintering behavior. The ultrafine particles have higher surface energy and can sinter at lower temperatures and for shorter durations, overcoming the hindrance caused by antioxidation treatment.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure where copper oxide particles are combined with organic antioxidants and binders. This composite material allows the copper oxide to maintain its reduced state while the organic components provide protection against oxidation and facilitate sintering through controlled decomposition.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If conventional photoresist method is used, then circuit pattern precision is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecircuit pattern precisionVSAvoidmanufacturing steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts and removes the photoresist step from the conventional manufacturing process. By using direct printing methods with copper oxide-based inks, the patent eliminates the need for photoresist application, exposure, and development steps, while still achieving precise circuit patterns through controlled deposition and sintering.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The copper oxide-based ink serves multiple functions: it provides the conductive material, acts as the pattern definition medium, and eliminates the need for separate photoresist and etching steps. This multi-functional approach simplifies the overall manufacturing process while maintaining precision.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The copper oxide ink achieves high dispersion stability, excellent storage stability, and the formation of conductive films with low resistance, addressing the limitations of existing technologies.

Implementation Method 1

reducing the copper oxide to copper by energy such as heat or active light rays in a suitable atmosphere

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 2

a dispersion in which microparticles selected from a group consisting of metal microparticles and metal oxide microparticles are dispersed

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

due to the decrease in the particular melting point of the metal ultrafine particles, sintering at a temperature lower than the melting point of the metal can be performed

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 4

irradiating the coating film with laser light

Methodology Applied
Scientific EffectLaser heating: Laser

Data Source

PatentUS12202996B2Copper oxide ink and method for producing conductive substrate using same, product containing coating film and method for producing product using same, method for producing product with conductive pattern, and product with conductive pattern
Publication Date: 2025.01.21 ASAHI KASEI KOGYO KABUSHIKI KAISHA
  • US12202996B2 patent drawing
  • US12202996B2 patent drawing
  • US12202996B2 patent drawing

AI summary

In the present invention, a conductive film having low resistance is formed on a substrate, said film having excellent storage stability and high dispersion stability as an ink. A copper oxide ink (1) contains a copper oxide (2), a dispersant (3), and a reducing agent. The content of the reducing agent is in the range of formula (1), and the content of the dispersant is in the range of formula (2). (1) 0.00010≤(reducing agent mass/copper oxide mass)≤0.10 (2) 0.0050≤(dispersant mass/copper oxide mass)≤0.30 The reducing agent content promotes the reduction of copper oxide to copper during firing, and promotes the sintering of copper.