Crossbar RRAM Electrodes with Large Grain Copper and Silver

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Solution Overview

Problem

Current RRAM technologies face challenges in achieving scalable, high-density, and high-speed non-volatile memory applications due to limitations in integrating resistive random access memory arrays with complementary metal oxide semiconducting (CMOS) circuits, particularly in miniaturizing the active device area and ensuring low line resistivity at smaller line widths.

Innovation Solution

The method involves depositing electrodes and metal films with large crystal grains in a crossbar array structure, utilizing highly conductive materials like copper and silver, and employing advanced processing techniques such as chemical mechanical planarization and etching to reduce electron scattering and enhance grain size, thereby achieving lower resistivity and scalability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional RRAM technologies are used, then integration with CMOS circuits is achieved, but scalability and miniaturization to 10 nanometers is limited

Engineering Contradiction:
Improveminiaturization precisionVSAvoidscalability
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent changes the material parameters by using copper and silver electrodes with large grain sizes instead of conventional materials, enabling miniaturization to 10 nanometers while maintaining low resistivity and improving scalability with CMOS circuits

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If line width is reduced for high-density memory, then storage density is improved, but line resistivity increases

Engineering Contradiction:
Improvestorage densityVSAvoidline resistivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the microstructural parameters of the electrode materials by creating large grain sizes in copper and silver films, which reduces electron scattering at grain boundaries and maintains low line resistivity even at reduced line widths for high-density storage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite electrode structures with copper or silver as the base material and incorporates specific grain structure characteristics, creating a composite material system that achieves both high storage density and low resistivity

Inventive Principle:
Principle #40Composite materials

3Reliability

If cycling endurance is improved for neuromorphic computing, then device reliability is enhanced, but device complexity increases

Engineering Contradiction:
Improvecycling enduranceVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the physical parameters of the electrode materials by optimizing grain size and crystal structure in copper and silver, which inherently improves cycling endurance for neuromorphic computing applications without requiring complex additional processing steps

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the miniaturization of RRAM devices to 10 nanometers, improves cycling endurance, and facilitates the integration of RRAM arrays with CMOS circuits, enhancing their scalability and performance for neuromorphic computing and memory applications.

Implementation Method 1

employing advanced processing techniques such as chemical mechanical planarization and etching to reduce electron scattering and enhance grain size, thereby achieving lower resistivity

Methodology Applied
Scientific EffectElectron scattering:

Data Source

PatentUS10141509B2Crossbar resistive memory array with highly conductive copper/copper alloy electrodes and silver/silver alloys electrodes
Publication Date: 2018.11.27 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US10141509B2 patent drawing
  • US10141509B2 patent drawing
  • US10141509B2 patent drawing

AI summary

Embodiments of the present invention provide systems and methods for the fabrication of a crossbar array fabrication of resistive random access memory (RRAM) cells. The array structure contains large grain copper and its alloy or silver and its alloy. A metal cap and spacer are used to protect copper or silver from chemical modifications during memory cell patterning.