Crosslinked Organic Light-Emitting Layers for Higher Emission Efficiency

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Solution Overview

Problem

Existing light emitting devices, such as organic electroluminescent devices, suffer from insufficient light emission efficiency.

Innovation Solution

A light emitting device comprising a cathode, a first organic layer with a compound having a cross-linkable group and a phosphorescent transition metal complex, and a second organic layer with a crosslinked body of the same compound, where the compound's cross-linkable group is present in a ratio of 2 to 10% by mass in the first organic layer, enhancing light emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If a conventional organic electroluminescent device structure is used, then the device can be manufactured with standard materials and processes, but the light emission efficiency is insufficient

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddevice performance sufficiency
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the organic layers by incorporating compounds with cross-linkable groups (at 2-10% by mass) and phosphorescent transition metal complexes, transforming the material properties to achieve higher light emission efficiency while maintaining device reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite organic layers by combining multiple components: compounds with cross-linkable groups, phosphorescent transition metal complexes, and other organic materials. This composite structure enables both improved light emission efficiency and sufficient device performance that conventional single-material layers cannot achieve

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If the first organic layer contains compound with cross-linkable group and phosphorescent transition metal complex at 2-10% by mass, then light emission efficiency is improved, but the manufacturing precision requirement increases

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidcomposition ratio control
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The patent establishes a specific mass ratio range (2-10%) for the compound with cross-linkable group in the first organic layer, optimizing this parameter to achieve high light emission efficiency while keeping the manufacturing precision requirement within feasible limits for industrial production

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device achieves improved light emission efficiency through the specific composition and structure of the organic layers, specifically utilizing cross-linkable groups and phosphorescent transition metal complexes.

Implementation Method 1

a first organic layer containing a compound having a cross-linkable group and a phosphorescent transition metal complex

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 2

a second organic layer containing a crosslinked body of the same compound as the compound having a cross-linkable group

Methodology Applied
Scientific EffectCrosslinking: Photopolymerisation

Data Source

PatentUS12161043B2Light emitting device
Publication Date: 2024.12.03 SUMITOMO CHEM CO LTD
  • US12161043B2 patent drawing
  • US12161043B2 patent drawing
  • US12161043B2 patent drawing

AI summary

A light emitting device having excellent light emission efficiency contains a cathode, a first organic layer containing a compound having a cross-linkable group and a phosphorescent transition metal complex, a second organic layer containing a crosslinked body of the same compound as the compound having a cross-linkable group, and an anode in this order. The ratio of the compound having a cross-linkable group contained in the first organic layer is 2 to 10% by mass with respect to the total mass of the first organic layer. The compound having a cross-linkable group may be a compound having at least one cross-linkable group selected from cross-linkable groups represented by the formula (XL-1) to the formula (XL-19).