Crosslinked Rubber Composition Balancing Softness and Resilience

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Solution Overview

Problem

Existing rubber compositions for enhancing resilience in golf balls do not achieve optimal softness and resilience performance simultaneously.

Innovation Solution

A rubber composition containing a base rubber, a co-crosslinking agent, a crosslinking initiator, and a salt of a benzothiazole derivative with a specific sulfur atom Mulliken charge, which accelerates crosslinking and improves resilience without compromising softness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional rubber compositions are used to enhance resilience, then the initial speed of the golf ball increases, but the softness of the core deteriorates

Engineering Contradiction:
ImproveresilienceVSAvoidsoftness
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical parameters of the crosslinking system by selecting specific accelerators (2-mercaptobenzothiazole or its salts) in combination with specific crosslinking agents. This parameter change in the chemical composition enables the rubber composition to achieve both high resilience and good softness simultaneously, resolving the contradiction between these two properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite crosslinking system by combining a crosslinking agent (such as zinc acrylate, zinc itaconate, or zinc maleate) with a specific accelerator (2-mercaptobenzothiazole or its salt). This composite approach allows the system to achieve both high crosslinking density for resilience and appropriate softness, as demonstrated in the embodiments where specific combinations yield both properties.

Inventive Principle:
Principle #40Composite materials

2Strength

If crosslinking density is increased to improve resilience, then the coefficient of restitution increases, but the compression deformation amount increases (reducing softness)

Engineering Contradiction:
Improvecoefficient of restitutionVSAvoidcompression deformation amount
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the chemical parameters of the crosslinking reaction by using specific accelerators and crosslinking agents. This enables achieving high crosslinking density (improving coefficient of restitution) while controlling the type of crosslinks formed to maintain appropriate compression deformation characteristics, thus resolving the contradiction between these two parameters.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates different local crosslinking characteristics within the rubber matrix by using a dual crosslinking system. The specific combination of crosslinking agent and accelerator produces a heterogeneous crosslinking structure that provides both high resilience (through dense crosslinking in certain regions) and appropriate softness (through controlled crosslinking density in other regions), as evidenced by the balanced performance in the embodiments.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition results in a crosslinked rubber molded product with enhanced resilience and maintained softness, as demonstrated by the relationship between coefficient of restitution and compression deformation amount.

Implementation Method 1

a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent, (c) a crosslinking initiator, and (d) a salt of a benzothiazole derivative

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent, (c) a crosslinking initiator

Methodology Applied
Scientific EffectInitiation of chemical reaction: Catalysis

Data Source

PatentUS12600837B2Rubber composition and crosslinked rubber molded product
Publication Date: 2026.04.14 SUMITOMO RUBBER INDUSTRIES LTD
  • US12600837B2 patent drawing
  • US12600837B2 patent drawing
  • US12600837B2 patent drawing

AI summary

An object of the present disclosure is to provide a rubber composition from which a crosslinked rubber molded product having good softness and excellent resilience performance can be obtained. The present disclosure provides a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent, (c) a crosslinking initiator, and (d) a salt of a benzothiazole derivative, wherein (d) the salt of the benzothiazole derivative includes a compound represented by the formula (1) in which a sulfur atom S2 constituting a thiocarbonyl group has a Mulliken charge of −0.190 or more.[In the formula (1), R1 to R4 are identical to or different from each other, and represent an electron-withdrawing group or a hydrogen atom, S1 and S2 represent a sulfur atom, X represents a cation component, n is an integer ranging from 1 to 4, and at least one of R1 to R4 bonding to the identical benzene ring is an electron-withdrawing group when n is 2 or more.]