Cyclic Amorphous Silicon Gapfill for High Aspect Ratio Trenches

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Solution Overview

Problem

Conventional amorphous silicon deposition methods fail to effectively gapfill high aspect ratio trenches in semiconductor devices, leading to seam and void formation due to uneven deposition rates, which can cause decreased throughput and device failure.

Innovation Solution

A method involving the deposition of amorphous silicon, followed by annealing to heal seams and etching to remove voids, with repeated cycles to achieve seamless and void-free gapfilling in high aspect ratio trenches.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional PECVD or conformal deposition methods are used to deposit amorphous silicon, then deposition speed is improved, but uneven deposition rates occur (higher at top, lower at bottom of trenches) resulting in seam formation

Engineering Contradiction:
Improvedeposition speedVSAvoiddeposition uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The deposition process is divided into multiple sequential cycles, each depositing a thin layer (e.g., 50-200 nm). After each cycle, an annealing step heals seams formed during that cycle's deposition. This segmentation allows control of seam formation at each stage while maintaining overall deposition speed.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process employs periodic alternation between deposition and annealing steps. Deposition creates the film layer by layer, while periodic annealing intervals heal seams before they propagate. This rhythmic cycle maintains both productivity and uniformity.

Inventive Principle:
Principle #19Periodic action

2Manufacturing precision

If thermal annealing is performed to heal seams in deposited film, then seam healing is improved, but film shrinking occurs and voids form inside trenches

Engineering Contradiction:
Improveseam healing qualityVSAvoidfilm dimensional stability
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

Annealing parameters (temperature, time, atmosphere) are precisely controlled and optimized to achieve seam healing while minimizing film shrinkage. The annealing temperature is maintained below the film's glass transition temperature where possible, and annealing time is limited to the minimum required for seam closure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The process creates a composite structure where multiple deposited layers are interleaved with annealed regions. Each cycle produces a layered composite of deposited material and healed material, building up the trench fill with controlled internal structure that minimizes void formation.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If aspect ratio of trenches increases to accommodate smaller device dimensions, then device scaling is improved, but post-curing becomes increasingly difficult and film composition varies throughout the trench

Engineering Contradiction:
Improvedevice scaling capabilityVSAvoidfilm composition uniformity
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The trench filling is segmented into multiple thin deposition cycles rather than attempting to fill the entire high aspect ratio trench in one step. Each cycle deposits a manageable thickness that can be properly cured and annealed, ensuring uniform composition throughout the trench depth.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each deposition cycle is followed by preliminary annealing and seam healing before the next layer is deposited. This preliminary treatment of each layer ensures proper curing and composition uniformity is established early, preventing composition variations from propagating through the entire trench fill.

Inventive Principle:
Principle #10Preliminary action

4Manufacturing precision

If multiple deposition cycles are performed to achieve uniform fill, then seam reduction is improved, but process time increases and throughput decreases

Engineering Contradiction:
Improveseam elimination qualityVSAvoidmanufacturing throughput
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

Each deposition cycle deposits slightly more material than strictly necessary to cover the previous layer, ensuring complete seam coverage. The annealing step is performed for the minimum time required to heal seams effectively. This balance achieves seam elimination while minimizing unnecessary process cycles.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

Deposition parameters (rate, temperature, pressure) and annealing parameters are optimized to achieve the desired film quality in the minimum number of cycles. By improving the efficiency of each individual cycle, the total process time is reduced while maintaining seam elimination quality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures seamless and void-free gapfilling in high aspect ratio trenches, enhancing the performance and reliability of semiconductor devices by eliminating defects caused by seam and void formation.

Implementation Method 1

depositing amorphous silicon over a semiconductor device having one or more features thereon

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

depositing amorphous silicon over a semiconductor device having one or more features thereon

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 3

annealing the deposited amorphous silicon to heal one or more seams in the deposited amorphous silicon between the one or more features

Methodology Applied
Scientific EffectThermal annealing: Annealing

Implementation Method 4

annealing the deposited amorphous silicon to heal one or more seams

Methodology Applied
Scientific EffectThermal diffusion: Diffusion

Implementation Method 5

etching the annealed amorphous silicon to remove one or more voids in the annealed amorphous silicon between the one or more features

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Data Source

PatentUS10510589B2Cyclic conformal deposition/anneal/etch for Si gapfill
Publication Date: 2019.12.17 APPLIED MATERIALS INC
  • US10510589B2 patent drawing
  • US10510589B2 patent drawing
  • US10510589B2 patent drawing

AI summary

Methods for seam and void-free gapfilling, such as gapfilling high aspect ratio trenches with amorphous silicon, are provided. A method generally includes depositing amorphous silicon over a semiconductor device having one or more features thereon, annealing the deposited amorphous silicon to heal one or more seams in the deposited amorphous silicon between the one or more features, and etching the annealed amorphous silicon to remove one or more voids in the annealed amorphous silicon between the one or more features. The deposition, anneal, and etch processes are generally repeated any suitable number of times to achieve amorphous silicon gapfill without any seam or void between the one or more features.