Date Palm Lignocellulose Hydrogels for Anionic Pollutant Adsorption

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Solution Overview

Problem

Water-scarce regions like Saudi Arabia face challenges in sustainable and cost-effective water treatment due to high costs and environmental impacts of traditional desalination and remediation methods, as well as pollution from improperly managed date palm waste.

Innovation Solution

Development of lignocellulose-based hydrogels derived from date palm waste, which are biodegradable, thermally stable, and have high adsorption capacity for contaminants, enabling efficient removal of toxic metals and organic pollutants from water and wastewater through adsorption processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional desalination and remediation methods (thermal processes and reverse osmosis) are used, then water treatment effectiveness is improved, but cost and environmental impact increase

Engineering Contradiction:
Improvewater treatment effectivenessVSAvoidcost-effectiveness
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical parameters of lignocellulose by controlling the degree of substitution (DS) and degree of polymerization (DP) during methacrylation and copolymerization. By adjusting these parameters, the hydrogel achieves optimal adsorption capacity for anionic pollutants while maintaining cost-effectiveness and biodegradability, resolving the contradiction between treatment effectiveness and cost

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite hydrogel material combining lignocellulose (natural polymer) with synthetic components (methacrylate groups, aziridine, and 4,4'-diselanediyldianiline). This composite structure provides both the effectiveness of advanced treatment methods and the cost-benefit of bio-based materials, while adding biodegradability and sustainability

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If date palm waste is improperly disposed of (burned or discarded), then waste management simplicity is improved, but environmental pollution increases

Engineering Contradiction:
Improvewaste disposal simplicityVSAvoidenvironmental pollution
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent converts date palm waste, which would otherwise be burned or discarded causing pollution, into a valuable resource for hydrogel production. The waste material is transformed into a functional adsorbent that removes pollutants from water, turning an environmental harm into a beneficial solution

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The hydrogel system enables date palm waste to serve its own purpose by using the waste-derived material to treat water contamination. The waste product becomes the treatment medium, creating a self-service cycle that eliminates the need for separate waste disposal processes

Inventive Principle:
Principle #25Self-service

3Quantity of substance

If petrochemical-based absorbents are used, then adsorption capacity is improved, but sustainability and biodegradability worsen

Engineering Contradiction:
Improveadsorption capacityVSAvoidbiodegradability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent achieves high adsorption capacity (qmax values for various anionic pollutants) by optimizing the chemical structure of the hydrogel through controlled methacrylation and copolymerization. The bio-based lignocellulose framework provides sufficient adsorption performance while maintaining biodegradability, eliminating the need for petrochemical-based absorbents

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The lignocellulose-based hydrogels provide a sustainable and cost-effective solution for water treatment, addressing pollution concerns and promoting waste management practices, ensuring a secure and healthy water supply while reducing environmental impact.

Implementation Method 1

The present subject matter relates to adsorption processes using bio-based membranes, specifically those derived from lignocellulose

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12084359B1Synthesis of positively charged hydrogels for anionic pollutant removal
Publication Date: 2024.09.10 KING FAISAL UNIV

AI summary

Lignocellulose based hydrogels (LCHs) derived from date palm (DP) waste that can be used to overcome water treatment challenges, as well as a preparation method and application thereof.