Deuterated Charge-Trap Memory Layer for Leakage Reduction

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Solution Overview

Problem

Conventional non-volatile semiconductor memory devices, such as SONOS transistors, face poor data retention due to leakage current through the nitride or oxy-nitride layer, leading to limited device lifetime and performance issues.

Innovation Solution

Incorporating a multi-layer charge-trapping region with a deuterated layer between the tunnel dielectric and charge-trapping layer, and optionally another deuterated layer between the charge-trapping layer and the top dielectric, to mitigate hot electron degradation and improve data retention by reducing voltage shifts during programming and erase cycles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional nitride or oxy-nitride layer is used as the charge-trapping layer, then the device can store charge, but leakage current through the layer causes poor data retention and limited device lifetime

Engineering Contradiction:
Improvedata retentionVSAvoidleakage current
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The charge-trapping layer is divided into multiple sub-layers with different compositions and functions. The first charge-trapping sub-layer (silicon-rich nitride) is optimized for charge storage, while the second charge-trapping sub-layer (oxygen-rich nitride) is optimized for reducing leakage current. This segmentation allows each sub-layer to specialize in one function, resolving the contradiction between charge storage capability and leakage reduction.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the charge-trapping layer are given different local properties. The first sub-layer has high trap density for charge storage, while the second sub-layer has lower trap density but better barrier properties against leakage. This local differentiation of properties enables simultaneous optimization of charge storage and leakage prevention that cannot be achieved with a uniform layer.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If silicon-rich SONOS layers are used, then a large initial separation between program and erase voltages is achieved, but charge storing ability deteriorates rapidly

Engineering Contradiction:
Improvevoltage separationVSAvoidcharge storing ability over time
Core Design Contradiction:
Measurement precisionVSDuration of action of stationary object

Solution Approach 1:

The charge-trapping functionality is segmented into two sub-layers: the first sub-layer provides strong voltage separation characteristics typical of silicon-rich nitride, while the second sub-layer provides stable charge storage over time. This segmentation resolves the contradiction by distributing different performance characteristics to different layers rather than requiring a single layer to optimize both simultaneously.

Inventive Principle:
Principle #1Segmentation

3Duration of action of stationary object

If oxygen-rich layers are used, then the rate of deterioration of charge storing ability is reduced, but the initial separation between program and erase voltages is reduced

Engineering Contradiction:
Improvecharge storing abilityVSAvoidvoltage separation
Core Design Contradiction:
Duration of action of stationary objectVSMeasurement precision

Solution Approach 1:

The charge-trapping layer is segmented so that the first sub-layer (silicon-rich) provides the necessary voltage separation, while the second sub-layer (oxygen-rich) provides stable charge storage with slow deterioration. This segmentation allows the device to achieve both good initial voltage separation and sustained charge storage capability over time.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances programming and erase speed while increasing data retention and extending the useful lifetime of the memory device by reducing leakage current and maintaining a suitable barrier to charge leakage.

Implementation Method 1

mitigate hot electron degradation and improve data retention by reducing voltage shifts during programming and erase cycles

Methodology Applied
Scientific EffectHot electron degradation:

Data Source

PatentUS10263087B2Nonvolatile charge trap memory device having a deuterated layer in a multi-layer charge-trapping region
Publication Date: 2019.04.16 LONGITUDE FLASH MEMORY SOLUTIONS LTD
  • US10263087B2 patent drawing
  • US10263087B2 patent drawing
  • US10263087B2 patent drawing

AI summary

A memory is described. Generally, the memory includes a number of non-planar multigate transistors, each including a channel of semiconducting material overlying a surface of a substrate and electrically connecting a source and a drain, a tunnel dielectric layer overlying the channel on at least three sides thereof, and a multi-layer charge-trapping region overlying the tunnel dielectric layer. In one embodiment, the multi-layer charge-trapping region includes a first deuterated layer overlying the tunnel dielectric layer and a first nitride-containing layer overlying the first deuterated layer. Other embodiments are also described.