Diffusion Bonding Surface Coating for Oxide-Free Metal Joining

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Solution Overview

Problem

Conventional diffusion bonding techniques face challenges when bonding metal or metal alloy workpieces with tenacious surface oxide layers, such as aluminium, due to issues like harsh cleaning processes, environmental hazards, grain coarsening, and less-than-optimum bond strengths, particularly for precision components.

Innovation Solution

A method involving coating the bonding surfaces with a liquid coating material that forms a stable barrier, abrades the oxide layer, removes excess material, and then diffuses the workpieces under controlled conditions, using environmentally-safe chemicals and avoiding extreme roughening or polymer coatings.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cleaning processes are used to remove surface oxide layers, then bonding surfaces can be prepared for diffusion bonding, but the cleaning processes are very harsh and environmentally harmful

Engineering Contradiction:
Improvebonding qualityVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A coating material is applied as an intermediary layer on the bonding surface before diffusion bonding. This coating material facilitates oxide removal and bonding while being environmentally safe, replacing harsh conventional cleaning processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the cleaning process by using a coating material that can be safely removed or decomposed, replacing traditional harsh chemicals with environmentally benign alternatives that achieve the same oxide removal function.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If grit blasting is used to prepare surfaces before diffusion bonding, then oxide layers are removed, but grain coarsening occurs at the bonding interface leading to lower bond strength

Engineering Contradiction:
Improveoxide removalVSAvoidbond strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The coating material serves as a mediator that enables oxide removal through chemical or mild mechanical means without the aggressive mechanical action of grit blasting, thereby preventing grain coarsening while still achieving effective oxide layer removal.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If electropolishing is used to prepare surfaces, then bonding quality is improved, but the process is undesirable for large scale use due to complexity

Engineering Contradiction:
Improvesurface qualityVSAvoidprocess scalability
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

Instead of using complex, expensive electropolishing equipment for large-scale production, the invention employs a simpler, more scalable coating application process that achieves comparable surface preparation results without the need for elaborate machinery.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Reliability

If polymer sealants are used in cleaning processes, then surface protection is achieved, but the sealants are environmentally harmful and may decompose during diffusion bonding leaving residues

Engineering Contradiction:
Improvesurface protectionVSAvoidenvironmental harm and residues
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the protective coating from harmful polymer sealants to environmentally safe materials that do not decompose into residues during diffusion bonding, maintaining surface protection while eliminating environmental harm.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Facilitates effective diffusion bonding of metal or metal alloy workpieces with tenacious surface oxide layers, ensuring strong bonds without environmental harm, eliminating the need for harsh cleaning or extreme roughening, and maintaining bond quality for precision components.

Implementation Method 1

the coating material is operable to form a stable barrier on the bonding surfaces of the metal or metal alloy containing workpieces under ambient conditions

Methodology Applied
Scientific EffectBarrier formation:

Implementation Method 2

evaporates from the bonding surfaces of the metal or metal alloy containing workpieces under diffusion bonding conditions

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

It utilises a combination of applied pressure (load) and elevated temperature to accelerate the diffusion of atoms across an interface and bond workpieces together

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11697174B2Diffusion bonding with a bonding surface coating material
Publication Date: 2023.07.11 TWI LTD
  • US11697174B2 patent drawing

AI summary

A method of diffusion bonding metal or metal alloy containing workpieces, comprises (a) coating the bonding surfaces of the metal or metal alloy containing workpieces with a layer of a coating material, (b) abrading the coated bonding surfaces to remove surface oxide, the coating material being in liquid form, (c) removing excess coating material or excess abraded metal or metal alloy containing workpiece material from the coated bonding surfaces, and (d) diffusion bonding the coated bonding surfaces of the metal or metal alloy containing workpieces together. The coating material is operable to form a stable barrier on the bonding surfaces of the metal or metal alloy containing workpieces under ambient conditions, and evaporates from the bonding surfaces under diffusion bonding conditions. There is also a bonded workpiece formed using the method of diffusion bonding metal or metal alloy containing workpieces.