Difunctional Monomer Ink Composition for Lithographic Plate Curing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current inkjet recording systems face challenges in achieving high sensitivity curing with UV radiation, leading to issues with image quality, flexibility, and adhesion of the cured ink composition to recording media, particularly in lithographic printing applications.

Innovation Solution

The use of a specific ink composition comprising difunctional (meth)acrylic acid esters or amides and difunctional vinyl ethers, combined with a polymerization initiator and colorant, which can be cured using actinic radiation, enhancing adhesion and flexibility while maintaining high sensitivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a large amount of polyfunctional monomer is used to maintain curing speed, then sensitivity to actinic radiation is improved, but flexibility of the cured image deteriorates

Engineering Contradiction:
Improvesensitivity to actinic radiationVSAvoidflexibility of cured image
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The invention changes the chemical parameters of the monomer components by selecting specific difunctional monomers with controlled reactivity and molecular structure. This allows achieving high curing sensitivity without relying on excessive polyfunctional monomer content, thereby maintaining flexibility in the cured image.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite monomer system comprising multiple difunctional monomers with different functional groups (acrylate, methacrylate, vinyl ether). This composite approach balances curing speed and flexibility by combining monomers with complementary properties, avoiding the need to use large amounts of highly reactive polyfunctional monomers alone.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional ink composition is used for inkjet recording, then equipment cost is low, but adhesion to recording medium deteriorates

Engineering Contradiction:
Improveequipment costVSAvoidadhesion to recording medium
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The invention modifies the chemical composition parameters of the ink by incorporating specific difunctional monomers that provide both good adhesion properties and compatibility with inkjet discharge systems. This maintains the simplicity and low cost of inkjet equipment while significantly improving adhesion strength to recording media.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional ink composition is used for lithographic printing plate, then production process is simple, but plate life deteriorates

Engineering Contradiction:
Improveproduction process complexityVSAvoidplate life
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The invention employs a composite monomer formulation that enhances the durability and longevity of lithographic printing plates. The specific combination of difunctional monomers creates a more robust cured image structure that withstands repeated printing cycles, extending plate life without complicating the production process.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves excellent adhesion to recording media, improved flexibility, and high sensitivity curing, resulting in enhanced image quality and extended plate life for lithographic printing plates.

Implementation Method 1

an ink composition which comprises (A) at least one type of polymerizable compound selected from the group consisting of a difunctional (meth)acrylic acid ester or amide having an alkylene group of 6 to 12 carbons, and a difunctional vinyl ether having an alkylene group of 6 to 12 carbons, (B) a polymerization initiator, and (C) a colorant

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS7935742B2Ink composition, inkjet recording method, process for producing lithographic printing plate, and lithographic printing plate
Publication Date: 2011.05.03 FUJIFILM CORP
  • US7935742B2 patent drawing
  • US7935742B2 patent drawing
  • US7935742B2 patent drawing

AI summary

An ink composition is provided that includes (A) one type of compound (monomer (A)) selected from the group consisting of a difunctional (meth)acrylic acid ester or amide having an alkylene group of 6 to 12 carbons, and a difunctional vinyl ether having an alkylene group of 6 to 12 carbons, (B) a polymerization initiator, and (C) a colorant. There is also provided an inkjet recording method that includes a step (a) of discharging the ink composition onto a recording medium and a step (b) of irradiating the discharged ink composition with actinic radiation so as to cure the ink composition. Furthermore, a process for producing a lithographic printing plate is provided that includes a step (a′) of discharging the ink composition onto a hydrophilic support and a step (b′) of irradiating the discharged ink composition with actinic radiation so as to cure the ink composition, thus forming a hydrophobic image on the hydrophilic support by curing the ink composition. A lithographic printing plate produced by the process for producing a lithographic printing plate is also provided.