Schottky Diode Silicide Nitride Stack for Surface Trap Suppression

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Solution Overview

Problem

The scaling down of semiconductor devices increases complexity and leads to current leakage due to surface traps formed during the formation of metallic layers in diodes, which affects the Schottky barrier and device performance.

Innovation Solution

Incorporating a stack of metal silicide nitride and metal silicide layers, where nitrogen atoms in the metal silicide nitride layer prevent the formation of surface traps by introducing nitrogen through a capping layer with a cubic crystal structure during the silicidation process, reducing current leakage by 10% to 50%.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If semiconductor devices are scaled down to increase storage capacity and processing speed, then device performance is improved, but manufacturing complexity increases and surface trap formation in metallic layers causes current leakage

Engineering Contradiction:
Improvestorage capacity and processing speedVSAvoidmanufacturing process complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by performing surface treatment with nitrogen-containing gas before the metallic layer is fully formed and before devices are scaled down. This pre-treatment prevents surface trap formation in advance, addressing the manufacturing complexity issue before it arises in the scaled-down devices. The nitrogen diffusion is initiated during the silicidation process itself, rather than requiring a separate post-processing step.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses nitrogen atoms as an intermediary substance that diffuses into the metallic layer during silicidation. This nitrogen intermediary prevents surface trap formation by modifying the metallic layer's surface properties. The nitrogen acts as a mediator between the silicidation process and the final diode performance, reducing current leakage without requiring complex manufacturing changes.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If metallic layers are formed during silicidation process, then electrical connectivity is achieved, but surface traps form causing current leakage that reduces device reliability

Engineering Contradiction:
Improvedevice reliabilityVSAvoidsurface traps and current leakage
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent converts the potentially harmful silicidation process into a beneficial opportunity by simultaneously introducing nitrogen during the same process. The silicidation that creates the metallic layer also provides the conditions for nitrogen diffusion that prevents surface trap formation. This transforms a process that normally generates harmful surface traps into one that simultaneously eliminates them.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent changes the chemical composition parameter of the metallic layer by introducing nitrogen atoms during silicidation. This parameter change modifies the surface properties of the metallic layer, preventing surface trap formation. The nitrogen concentration in the metallic layer is controlled to optimize both the prevention of surface traps and the maintenance of electrical connectivity.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If nitrogen-based surface treatment is applied during silicidation, then surface traps are prevented and current leakage reduces by 10% to 50%, but process parameters must be precisely controlled

Engineering Contradiction:
Improvecurrent leakageVSAvoidprocess parameter control
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent merges the nitrogen-based surface treatment with the silicidation process into a single unified operation. Instead of being separate sequential steps, the nitrogen diffusion and metallic layer formation occur simultaneously during the same processing window. This merging reduces the number of process parameters that need independent control and simplifies the overall manufacturing precision requirements.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of metal silicide nitride layers effectively mitigates surface traps, enhancing diode performance by reducing current leakage and maintaining the Schottky barrier, thus improving device reliability and efficiency.

Implementation Method 1

forms a cubic crystal structure capping layer to facilitate nitrogen diffusion

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20240234589A1Surface damage control in diodes
Publication Date: 2024.07.11 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20240234589A1 patent drawing
  • US20240234589A1 patent drawing
  • US20240234589A1 patent drawing

AI summary

A semiconductor device and a method of forming the same is disclosed. The semiconductor device includes a substrate, a first well region disposed within the substrate, a second well region disposed adjacent to the first well region and within the substrate, and an array of well regions disposed within the first well region. The first well region includes a first type of dopants, the second well region includes a second type of dopants that is different from the first type of dopants, and the array of well regions include the second type of dopants. The semiconductor device further includes a metal silicide layer disposed on the array of well regions and within the substrate, a metal silicide nitride layer disposed on the metal silicide layer and within the substrate, and a contact structure disposed on the metal silicide nitride layer.