Genetically Engineered Bacteria with Disrupted CODH Genes

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Solution Overview

Problem

Efficient production of fuels like ethanol and chemicals such as 2,3-butanediol from gaseous substrates like CO, CO2, and H2 is limited by diversion of carbon substrates into undesired byproducts and slow microorganism growth in existing microorganisms.

Innovation Solution

Genetically engineered carboxydotrophic acetogenic bacteria with decreased or eliminated carbon monoxide dehydrogenase (CODH) activity, specifically through disruptive mutations in CODH1 and/or CODH2 genes, and increased CODH/ACS activity, allowing for improved product profiles and growth characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If CODH1 and CODH2 genes are disrupted to decrease CODH activity, then ethanol and 2,3-butanediol production is improved, but acetate production increases as an undesired byproduct

Engineering Contradiction:
Improveethanol and 2,3-butanediol productionVSAvoidacetate byproduct formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful function of CODH1 and CODH2 enzymes by disrupting their genes, thereby eliminating the side reaction that produces acetate while preserving the desired fuel and chemical production pathways

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the activity parameter of CODH enzymes from active to inactive state through genetic disruption, fundamentally altering the metabolic flux distribution to favor ethanol and 2,3-butanediol production over acetate formation

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If CODH1 and CODH2 genes are disrupted to improve product profile, then microorganism growth rate decreases and lag phase increases

Engineering Contradiction:
Improveproduct profileVSAvoidgrowth rate
Core Design Contradiction:
Manufacturing precisionVSSpeed

Solution Approach 1:

The patent changes the metabolic state parameters of the microorganism by disrupting CODH genes, which fundamentally alters the growth kinetics and product formation characteristics to achieve superior product profiles despite initial growth adjustments

Inventive Principle:
Principle #35Parameter changes

3Productivity

If carbon substrates are diverted into undesired byproducts, then fuel and chemical production efficiency decreases, but microorganism growth may be maintained

Engineering Contradiction:
Improvefuel and chemical production efficiencyVSAvoidcarbon substrate diversion to byproducts
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent extracts and eliminates the metabolic pathway responsible for carbon diversion to acetate by disrupting CODH genes, thereby channeling all carbon substrates toward the desired fuel and chemical production pathways

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent discards the acetate production pathway by disabling CODH enzymes, thereby recovering and redirecting carbon substrates that would have been lost to byproducts into valuable fuel and chemical synthesis

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The genetically modified bacteria produce higher amounts of ethanol and 2,3-butanediol, have a shorter lag phase, and increased growth rate compared to parental bacteria, while reducing acetate production, thereby enhancing fermentation efficiency.

Implementation Method 1

Certain microorganisms can produce fuels, such as ethanol, and other chemicals, such as 2,3-butanediol, by fermentation of gaseous substrates comprising one or more of carbon monoxide (CO), carbon dioxide (CO2), and hydrogen (H2)

Methodology Applied
Scientific EffectFermentation: Fermentation

Implementation Method 2

carbon monoxide dehydrogenase (CODH) activity

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3180421B1Genetically engineered bacterium with decreased carbon monoxide dehydrogenase (CODH) activity
Publication Date: 2019.03.27 LANZATECH NEW ZEALAND LTD
  • EP3180421B1 patent drawingFigure 1(A)~1(D)
  • EP3180421B1 patent drawingFigure 2A~2C
  • EP3180421B1 patent drawingFigure 3A~4

AI summary

The invention provides genetically engineered microorganisms with altered carbon monoxide dehydrogenase (CODH) activity and methods related thereto. In particular, the invention provides a genetically engineered carboxydotrophic acetogenic bacterium having decreased or eliminated activity of CODH1 and/or CODH2. In certain embodiments, the bacterium may also have increased activity of CODH/ACS. The invention further provides a method for producing a product by culturing the bacterium in the presence of a gaseous substrate comprising one or more of carbon monoxide, carbon dioxide, and hydrogen.