Dual Conversion Dynode Ion Detector for Mass Spectrometer Polarity Switching

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Solution Overview

Problem

Current mass spectrometer detectors face challenges in rapidly switching between positive and negative ion polarity detection without incurring high costs, high power consumption, and increased size due to the need for rapid voltage switching of conversion dynodes.

Innovation Solution

A dual-polarity ion detector configuration using two conversion dynodes with opposite polarities and a shielding electrode, allowing ions to follow specific trajectories based on their polarity without the need for voltage switching, thereby reducing polarity switching time and hardware complexity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If rapid voltage switching of conversion dynodes is used to switch between positive and negative ion polarity detection, then polarity switching speed is improved, but cost, power consumption, and device size increase

Engineering Contradiction:
Improvepolarity switching speedVSAvoidhardware complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The detector is divided into two separate conversion dynodes: a first conversion dynode for detecting ions of a first polarity and a second conversion dynode for detecting ions of a second polarity. This segmentation eliminates the need for rapid voltage switching of a single dynode, as each dynode is optimized for a specific polarity, thereby resolving the contradiction between switching speed and hardware complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Instead of using a single conversion dynode that switches polarity through rapid voltage changes, the invention inverts the approach by using two fixed-polarity dynodes that simultaneously handle both polarities. The polarity selection is achieved through ion trajectory guidance rather than dynode voltage switching, reducing hardware complexity while maintaining fast switching capability

Inventive Principle:
Principle #13The other way round (Inversion)

2Speed

If rapid voltage switching of conversion dynodes is used to switch between positive and negative ion polarity detection, then polarity switching speed is improved, but power consumption increases

Engineering Contradiction:
Improvepolarity switching speedVSAvoidpower consumption
Core Design Contradiction:
SpeedVSUse of energy by stationary object

Solution Approach 1:

By segmenting the detection function across two fixed-polarity conversion dynodes, the system eliminates the need for high-power rapid voltage switching. Each dynode operates at a stable voltage optimized for its designated polarity, significantly reducing power consumption while maintaining fast polarity switching through passive ion trajectory guidance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention replaces the active electrical switching mechanism (rapid voltage changes) with a passive mechanical/field-based guidance system that directs ions to the appropriate dynode based on their polarity. This substitution eliminates the high power consumption associated with rapid voltage switching while maintaining fast response

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Speed

If rapid voltage switching of conversion dynodes is used to switch between positive and negative ion polarity detection, then polarity switching speed is improved, but device size increases

Engineering Contradiction:
Improvepolarity switching speedVSAvoiddetector size
Core Design Contradiction:
SpeedVSVolume of moving object

Solution Approach 1:

The detector volume is efficiently segmented into two functional zones, each handled by a dedicated conversion dynode. This segmentation allows for compact integration of both polarity detection capabilities within a single detector housing, eliminating the need for oversized voltage switching circuitry while maintaining fast switching performance

Inventive Principle:
Principle #1Segmentation

4Loss of time

If dual-polarity detection is implemented with separate dynodes for each polarity, then polarity switching time is reduced, but device complexity increases

Engineering Contradiction:
Improvepolarity switching timeVSAvoiddetector configuration complexity
Core Design Contradiction:
Loss of timeVSDevice complexity

Solution Approach 1:

The detector achieves multi-functionality by incorporating two conversion dynodes that simultaneously handle both positive and negative ion detection. This universal design eliminates the need for complex switching mechanisms, as the detector inherently supports both polarities through its dual-dynode configuration, reducing switching time without proportionally increasing complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables fast and cost-effective polarity switching, reducing the polarity switching time to a few microseconds, simplifying the design, and minimizing power consumption and cooling requirements, while maintaining robust performance.

Implementation Method 1

A first conversion dynode in the detector directs positive ions to generate secondary electrons. A second conversion dynode in the detector directs negative ions to generate secondary positive ions.

Methodology Applied
Scientific EffectSecondary emission:

Data Source

PatentUS20230105334A1High-speed polarity switching dual conversion dynode ion detector for mass spectrometer
Publication Date: 2023.04.06 THERMO FINNIGAN LLC
  • US20230105334A1 patent drawing
  • US20230105334A1 patent drawing
  • US20230105334A1 patent drawing

AI summary

A dual polarity ion detector comprises: an entrance electrode disposed to receive ions and maintained at a reference voltage, V0; a first dynode maintained at a voltage, V1, that is negative relative to V0; a second dynode maintained at a voltage, V2, that is positive relative to V0; a shielding electrode disposed between the first and second dynodes and maintained at a voltage, V3; and an ion detector comprising an entrance aperture configured to receive first secondary particles from the first dynode and second secondary particles from the second dynode, the entrance aperture maintained at a voltage, Vaperture; that is intermediate between the voltage, V1, and the voltage, V2. In some instances, the voltage, V3, may be equal to or approximately equal to the voltage, V0.