Dual-Host Organic Light-Emitting Device Emission Layer

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving balanced electron and hole transport, which affects efficiency and lifespan, particularly when relying on a single host material in the emission layer.

Innovation Solution

Incorporating a first host and a second host in the emission layer, where the first host includes an electron transport group and the second host includes a hole transport group, with specific chemical structures represented by Formulas 1 and 2, to improve efficiency and lifespan by ensuring balanced charge transport.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single host material is used in the emission layer, then the device structure is simple, but the charge transport becomes unbalanced leading to reduced efficiency and lifespan

Engineering Contradiction:
Improveemission layer structureVSAvoidcharge transport balance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The emission layer is segmented into multiple functional components: a first host material (Formula 1) providing electron transport capability and a second host material (Formula 2) providing hole transport capability. This segmentation allows each host material to specialize in transporting one type of charge carrier, achieving balanced charge transport while maintaining a relatively simple overall layer structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite materials by combining two different host materials with complementary transport properties in the emission layer. The first host (Formula 1) with electron transport groups and the second host (Formula 2) with hole transport groups work synergistically to achieve balanced electron and hole transport, improving device reliability without significantly increasing structural complexity.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If a single host material is used in the emission layer, then the material selection is simple, but the efficiency and lifespan are compromised

Engineering Contradiction:
Improvematerial selectionVSAvoiddevice efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent applies local quality by assigning specific functional properties to different host materials at different locations within the emission layer. The first host material (Formula 1) is specifically designed with electron transport groups for efficient electron transport, while the second host material (Formula 2) is designed with hole transport groups for efficient hole transport. This localized functional specialization optimizes overall device efficiency.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by modifying the chemical structure of host materials to achieve desired transport properties. Formula 1 incorporates electron transport groups (such as triphenylamine, carbazole, or BPhen structures) while Formula 2 incorporates hole transport groups, thereby changing the electrical parameters of the emission layer to achieve balanced charge transport and improved efficiency.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If a single host material is used in the emission layer, then the device structure is straightforward, but the lifespan is reduced due to unbalanced charge transport

Engineering Contradiction:
Improveemission layer compositionVSAvoiddevice lifespan
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The emission layer is segmented into multiple functional components: a first host material (Formula 1) providing electron transport capability and a second host material (Formula 2) providing hole transport capability. This segmentation allows each host material to specialize in transporting one type of charge carrier, achieving balanced charge transport while maintaining a relatively simple overall layer structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The dual-host structure acts as a preventive measure against the formation of charge accumulation and imbalanced transport that would otherwise occur in single-host devices. By anticipating and preventing charge transport imbalance through the complementary host material combination, the device lifespan is extended before degradation can occur.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This dual-host approach enhances the efficiency and lifespan of organic light-emitting devices by ensuring balanced electron and hole transport, improving emission characteristics and device performance.

Implementation Method 1

The organic light-emitting device may include a first electrode disposed on a substrate, and a hole transport region, an emission layer, an electron transport region, and a second electrode, which are sequentially disposed on the first electrode. Holes provided from the first electrode may move toward the emission layer through the hole transport region, and electrons provided from the second electrode may move toward the emission layer through the electron transport region. The holes and the electrons are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9917262B2Organic light-emitting device
Publication Date: 2018.03.13 SAMSUNG DISPLAY CO LTD
  • US9917262B2 patent drawing
  • US9917262B2 patent drawing
  • US9917262B2 patent drawing

AI summary

An organic light-emitting device including a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer; wherein the emission layer includes a first host represented by the following Formula 1, and a second host represented by the following Formula 2: