Dual-Layer Plasma Coating with Embedded Sensor for Polymeric Transparency

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Solution Overview

Problem

Current wear-resistant coatings for polymeric transparencies, such as those used in aircraft windows, lack durability and optical clarity, and there is no non-destructive method to monitor their integrity, leading to potential exposure of the substrate to abrasion and chemical degradation.

Innovation Solution

A dual-layer transparent plasma-based coating system comprising a soft SiOxCy coating and a hard SiOxCy coating, with a sensor embedded between the layers, deposited using plasma deposition, providing enhanced durability and a means to monitor the coating's condition through changes in electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a single hard coating is applied to improve abrasion resistance, then wear resistance improves, but flexibility and adhesion to the polymeric substrate deteriorate

Engineering Contradiction:
Improveabrasion resistanceVSAvoidflexibility
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The coating system is divided into two distinct layers: a soft flexible coating layer in direct contact with the polymeric substrate that provides adhesion and flexibility, and a hard coating layer on the outer surface that provides abrasion resistance. This segmentation allows each layer to perform its specialized function without compromising the other properties.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite coating structure combining materials with different mechanical properties - a softer polymer-based coating material for flexibility and adhesion, combined with a harder coating material for wear resistance. This composite approach creates a multi-functional coating system that simultaneously achieves flexibility and hardness.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If a thick hard coating is applied to improve durability, then wear resistance improves, but optical clarity deteriorates

Engineering Contradiction:
ImprovedurabilityVSAvoidoptical clarity
Core Design Contradiction:
Duration of action of stationary objectVSIllumination intensity

Solution Approach 1:

The coating is segmented into functional layers with the hard protective layer optimized for durability and the outer layer optimized for optical properties. This allows the hard coating to provide protection without needing to be excessively thick, as the layered structure distributes the functional requirements.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention optimizes the thickness parameters of each coating layer to achieve the desired balance between durability and optical clarity. By controlling the thickness of the hard coating layer and the outer layer, the system maintains optical transparency while providing sufficient wear protection.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If traditional sol-gel coatings are used to protect polymeric transparencies, then application simplicity improves, but durability against wear and UV degradation worsens

Engineering Contradiction:
Improveapplication simplicityVSAvoiddurability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The coating system uses a composite formulation combining organosilane, alkoxide, and polymer components that work synergistically to provide both ease of application and superior durability. The composite nature of the coating allows it to form a robust protective layer with enhanced wear and UV resistance compared to traditional sol-gel coatings.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the chemical composition parameters of the coating system, incorporating specific ratios of organosilane to alkoxide and adding polymer components, to enhance the cross-linking density and network structure. This results in improved durability while maintaining the sol-gel process's simplicity and compatibility with temperature-sensitive substrates.

Inventive Principle:
Principle #35Parameter changes

4Device complexity

If no sensor is embedded in the coating, then device complexity is reduced, but the ability to detect coating deterioration worsens

Engineering Contradiction:
Improvecoating structure simplicityVSAvoidcoating integrity monitoring
Core Design Contradiction:
Device complexityVSDifficulty of detecting and measuring

Solution Approach 1:

An electromagnetic sensor layer is embedded within the coating structure to act as an intermediary that detects changes in coating integrity. This sensor layer provides a means to monitor the coating's condition without requiring complex external monitoring systems, as the sensor is integrated directly into the coating matrix.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The embedded sensor provides feedback about the coating's structural integrity and performance status. This feedback mechanism allows for real-time or periodic monitoring of the coating condition, enabling timely detection of deterioration and prompting maintenance or replacement before significant damage occurs to the underlying substrate.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system significantly improves abrasion resistance and optical clarity, maintaining the substrate's integrity by detecting deterioration through electrical conductivity changes, ensuring prolonged component lifetime and safety in critical applications.

Implementation Method 1

The coating layers are deposited in a plasma process

Methodology Applied
Scientific EffectPlasma deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 2

monitoring the electrical conductivity of a sensor embedded within the coating, wherein the coating comprises at least one soft coating layer and at least one hard coating layer

Methodology Applied
Scientific EffectElectrical conductivity: Conduction (electrical)

Data Source

PatentEP2960301B1Durable transparent intelligent coatings for polymeric transparencies
Publication Date: 2017.08.23 THE BOEING CO
  • EP2960301B1 patent drawingFigure 1~1A
  • EP2960301B1 patent drawingFigure 1B~1C
  • EP2960301B1 patent drawingFigure 2~3

AI summary

A hard, transparent coating for a substrate and associated method for coating is disclosed. The coating includes alternating layers of a soft coating and a hard coating. The coating further includes a sensor. The electrical resistivity of the sensor may be measured to determine if the coating has been degraded. The coating may further include a hydrophobic outer layer.