Organic EL Element Intermediate Layer Dopant Distribution

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Solution Overview

Problem

Existing organic electroluminescence (EL) elements face challenges in achieving balanced RGB light emission due to high electron transportability of host materials in blue light-emitting layers, leading to premature degradation and poor luminescence characteristics.

Innovation Solution

A light-emitting element configuration with a red, intermediate, and blue light-emitting layers, where the intermediate layer contains a host material and an assist dopant with high electron transportability, and the blue and green light-emitting layers contain host and assist dopant materials with opposite mobility, ensuring balanced carrier transport and suppressing hole passage to the cathode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a host material with high electron transportability is used in the blue light-emitting layer, then electron transport efficiency is improved, but the recombination region concentrates at the interface with the intermediate layer causing rapid degradation

Engineering Contradiction:
Improveelectron transport efficiencyVSAvoidlifetime of blue light-emitting layer
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent applies local quality by creating distinct regions with different material properties within the light-emitting layers. The intermediate layer has high electron transportability to efficiently transport electrons, while the blue and green light-emitting layers have balanced electron and hole transportability to achieve uniform carrier recombination distribution. This spatial variation in material properties resolves the contradiction by localizing high electron transportability only where needed (intermediate layer) while maintaining reliability in other regions.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the transportability parameters of different layers to resolve the contradiction. Specifically, it adjusts the electron and hole transportability ratios (μe/μh) of the blue and green light-emitting layers to be within 0.01 to 100, which prevents excessive concentration of recombination regions. Simultaneously, the intermediate layer maintains high electron transportability for efficient electron transport. This parameter optimization resolves the contradiction between speed and reliability.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If multiple light-emitting layers with different colors are embedded in one organic EL element, then white light emission is achieved, but balanced light emission from all RGB layers is difficult to obtain

Engineering Contradiction:
Improvewhite light emission capabilityVSAvoidbalanced light emission
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies local quality by assigning different material compositions and transportability characteristics to each light-emitting layer (red, green, blue) and the intermediate layer. Each layer is optimized with specific electron and hole transportability ratios to ensure uniform carrier recombination and balanced light emission from all colors. This localized optimization of material properties enables all RGB layers to contribute equally to white light emission, resolving the contradiction between versatility and balanced performance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials strategy by combining multiple light-emitting layers with different color emissions (red, green, blue) and an intermediate layer with specific transport properties. This composite structure allows each layer to contribute its specific color while the intermediate layer ensures balanced carrier distribution, achieving both white light emission capability and balanced light output from all layers.

Inventive Principle:
Principle #40Composite materials

3Productivity

If the recombination region is concentrated at the interface between intermediate layer and blue light-emitting layer, then electron transport efficiency is improved, but degradation of blue light-emitting layer progresses rapidly

Engineering Contradiction:
Improveelectron transport efficiencyVSAvoidlifetime of blue light-emitting layer
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent applies local quality by creating a spatial distribution of recombination regions throughout the blue and green light-emitting layers rather than concentrating them at the interface. This is achieved by optimizing the electron and hole transportability ratios of these layers to be within 0.01 to 100, which ensures uniform carrier injection and recombination distribution. The intermediate layer maintains high electron transportability for efficient electron transport, while the light-emitting layers have balanced transport properties to distribute recombination uniformly, thus improving both productivity and durability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies beforehand cushioning by designing the blue and green light-emitting layers with balanced electron and hole transportability before the degradation problem occurs. This preventive design ensures that carrier recombination is uniformly distributed from the beginning of device operation, preventing the concentration of stress and degradation at specific interfaces. The optimized transportability ratios act as a cushion against premature degradation, extending the device lifetime while maintaining efficient electron transport.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances luminescence characteristics and extends the lifetime of the light-emitting element by preventing premature degradation and ensuring balanced light emission.

Implementation Method 1

An organic electroluminescence element (so-called organic EL element) is a light-emitting element having a structure in which a luminescent organic layer of at least one layer is interposed between an anode and a cathode. When an electric field is applied between a cathode and an anode, electrons are injected into a light-emitting layer from the cathode and holes are injected into the light-emitting layer from the anode, and thus the electrons and holes are recombined in the light-emitting layer, that is, carriers are recombined to generate excitons. When these excitons return to a ground state, the energy content is emitted as light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9293724B2Light-emitting element, light-emitting device, display device, and electronic apparatus
Publication Date: 2016.03.22 SEIKO EPSON CORP
  • US9293724B2 patent drawing
  • US9293724B2 patent drawing
  • US9293724B2 patent drawing

AI summary

Disclosed herein is a light-emitting element, including: a cathode; an anode; and a light-emitting unit, in which the light-emitting unit includes a first light-emitting layer, an intermediate layer, a second light-emitting layer, and a third light-emitting layer, which are laminated from the anode side to the cathode side, in which each of the second and third light-emitting layers is configured to contain a luminescent material, a host material, and an assist dopant material, in which the intermediate layer is configured to contain the host material and the assist dopant material, and in which, when the concentrations of the assist dopant materials contained in the second light-emitting layer, the third light-emitting layer, and the intermediate layer are respectively expressed by CAssist(EML2), CAssist(EML3), and CAssist(IML), the following Relational Expression (A) is satisfied:CAssist(IML)>CAssist(EML2)≧CAssist(EML3)  (A).