Electroformed Nickel Composite Components for High-Temperature Applications

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Solution Overview

Problem

Current electroforming technologies are limited by the restricted material options available for high-temperature structural components, which restrict the operating temperature of electroformed components to approximately 500° F (260° C), limiting their strength and temperature capability compared to conventional alloys.

Innovation Solution

The method involves incorporating reinforcing phases, such as nanoscale particles, into the electrolyte during electroforming to create composite materials that enhance the strength and temperature stability of electroformed components, allowing them to operate up to or beyond 1200° F (650° C) by using a nickel-based matrix with particles like yttria, alumina, or carbon nanotubes, and their precursors, which are stable and well-dispersed in the matrix.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional electroforming materials are used, then the manufacturing process is simple and low-cost, but the operating temperature is limited to approximately 500° F (260° C)

Engineering Contradiction:
Improveoperating temperatureVSAvoidmaterial options
Core Design Contradiction:
TemperatureVSAdaptability or versatility

Solution Approach 1:

The patent applies composite materials by combining a nickel-based matrix with reinforcing particles (yttria, alumina, or carbon nanotubes) to create an electroformed component that can operate at temperatures up to 1200° F (650° C) or higher, thereby resolving the contradiction between limited material options and high-temperature capability

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If dispersants are added to the electrolyte to improve particle dispersion, then particle distribution improves, but maximum use temperature is limited

Engineering Contradiction:
Improveparticle dispersionVSAvoidmaximum use temperature
Core Design Contradiction:
Stability of the object's compositionVSTemperature

Solution Approach 1:

The patent extracts/removes dispersants from the electrolyte system entirely, instead relying on the natural stability and dispersion characteristics of the precursor particles in the electrolyte solution, thereby eliminating the temperature limitation imposed by dispersant decomposition

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The precursor particles self-disperse in the electrolyte without requiring external dispersant agents, utilizing their inherent properties to achieve stable suspension and uniform distribution during the electroforming process

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of electroformed components with improved strength and high-temperature capability, exceeding the limitations of existing materials, enabling new applications in aerospace and other fields by maintaining low residual stress and high current efficiency without the need for dispersants, which can limit maximum use temperature.

Implementation Method 1

Electroforming is an additive manufacturing process where metal parts are formed through electrolytic reduction of metal ions (atom by atom) on the surface of a mandrel (cathode)

Methodology Applied
Scientific EffectElectrolytic reduction: Electrolysis

Implementation Method 2

passing an electric current between an anode and a cathode in the presence of an electrolyte, depositing a composite layer on the cathode

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Data Source

PatentUS11788198B2Methods of forming high-temperature electroformed components and related components
Publication Date: 2023.10.17 GENERAL ELECTRIC CO
  • US11788198B2 patent drawing
  • US11788198B2 patent drawing
  • US11788198B2 patent drawing

AI summary

An electroformed composite component includes reinforcing particles in a metal matrix. The composite component is formed by a method including passing an electric current between an anode and a cathode in the presence of an electrolyte. The electrolyte includes a metal salt and a plurality of reinforcing particle precursors. The method further includes depositing a composite layer on the cathode, wherein the composite layer includes the metal matrix and the plurality of reinforcing particle precursors dispersed in the metal matrix. An optional heat treatment can be performed subsequently to transform the precursor particles to more stable forms with concomitant improvement in composite material properties.