Embedded Raman Probe for Multi-Phase Flow Composition Analysis

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Solution Overview

Problem

Conventional offshore plant and flow loop systems lack the capability to detect the composition of multi-phase flowing fluids in real time, making it difficult to predict and prevent hydrate plugging, which leads to operational inefficiencies and increased costs.

Innovation Solution

An embedded measuring device with Raman probes and a Raman peak analysis unit is used to determine the composition and predict hydrate formation in real time by measuring Raman peak intensity within the pipeline, allowing for precise analysis of gas and liquid components and controlling pressure and temperature to prevent plugging.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional measuring instruments and visual observation via monitoring window are used, then fluid characteristics (pressure, temperature, flow rate) can be measured, but real-time composition analysis and hydrate formation detection are impossible

Engineering Contradiction:
Improvecomposition analysis capabilityVSAvoidmeasurement system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The Raman probe is embedded within the pipeline structure, with the optical fiber probe nested inside the pipeline wall. This allows the measurement device to be integrated into the existing pipeline without requiring separate external measurement systems, thereby improving measurement precision while avoiding excessive device complexity

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent replaces conventional mechanical sampling and laboratory analysis systems with an optical-based Raman spectroscopy system. The Raman probe uses light scattering to directly analyze fluid composition in-situ, eliminating the need for physical sample collection, transport, and manual analysis, thus enabling real-time composition analysis without proportionally increasing system complexity

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If chromatography method is used to analyze fluid components, then qualitative and quantitative analysis can be performed, but real-time analysis is impossible and excessive analysis time is required

Engineering Contradiction:
Improvecomponent analysis accuracyVSAvoidanalysis time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent replaces the mechanical chromatography separation system with an optical Raman spectroscopy system. Raman spectroscopy directly measures molecular vibrations to identify and quantify components without requiring physical separation, reducing analysis time from hours to seconds while maintaining compositional analysis accuracy

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The Raman probe continuously monitors fluid composition in real-time before hydrate formation occurs, enabling early detection and preventive action. This preliminary monitoring capability allows operators to take corrective measures before plugging problems develop, eliminating the time loss associated with reactive problem-solving

Inventive Principle:
Principle #10Preliminary action

3Reliability

If monitoring window is used to visually observe hydrate formation, then plugging phenomenon can be observed, but initial hydrate cannot be distinguished from particles and prevention opportunity is lost

Engineering Contradiction:
Improveplugging detection reliabilityVSAvoidhydrate detection difficulty
Core Design Contradiction:
ReliabilityVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces visual observation through a monitoring window with Raman spectroscopic detection. The Raman probe identifies hydrate formation by detecting characteristic molecular vibration signatures of hydrate structures, which are distinct from particles or other contaminants. This spectral fingerprinting capability allows reliable detection of initial hydrate formation that is invisible to the naked eye

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The Raman probe acts as an intermediary between the fluid and the monitoring system. Instead of directly observing hydrate crystals through a window, the probe measures molecular-level changes in the fluid composition and properties that precede visible hydrate formation, providing early warning before plugging occurs

Inventive Principle:
Principle #24Intermediary (Mediator)

4Productivity

If pipeline is cut away when plugging occurs, then operational continuity can be maintained, but enormous expenses are required and this is not a fundamental solution

Engineering Contradiction:
Improveoperational continuityVSAvoideconomic loss
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The Raman-based monitoring system performs preliminary detection of hydrate formation and compositional changes that precede plugging. By identifying these early warning signs, the system enables preventive actions such as adjusting flow conditions, adding inhibitors, or heating the pipeline before plugging occurs, thereby maintaining operational continuity without the need for expensive pipeline cutting and replacement

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system provides continuous feedback on fluid composition, temperature, and hydrate formation tendency. This real-time feedback allows operators to adjust operational parameters dynamically to prevent plugging, transforming the approach from reactive (cutting pipelines after failure) to proactive (maintaining conditions that prevent failure), thus improving productivity while reducing economic losses

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time determination of multi-phase fluid composition and prediction of hydrate formation, enhancing operational efficiency and preventing plugging phenomena, thereby ensuring economical and efficient offshore plant operations.

Implementation Method 1

determined by measuring Raman peak intensity of the multi-phase flowing fluid within the pipeline using the Raman probe

Methodology Applied
Scientific EffectRaman scattering: Rayleigh Scattering

Data Source

PatentUS9606063B2Embedded device for measuring component and composition of multi-phase flow fluid flowing in pipe
Publication Date: 2017.03.28 KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY
  • US9606063B2 patent drawing
  • US9606063B2 patent drawing
  • US9606063B2 patent drawing

AI summary

An embedded measurement device that is capable of measuring the component and a composition of a multi-phase flow fluid flowing in a pipe. The embedded measurement device includes: a high-pressure pipe tube in which the multi-phase flow fluid flows; a Raman probe that is partially inserted inside the high-pressure pipe tube and has an optical lens; and a Raman peak analysis unit that is connected to another part of the Raman probe. The device for measuring the composition of the multi-phase flow fluid measures a Raman peak intensity value of the multi-phase flow fluid in the high-pressure pipe tube by using the Raman probe, thereby determining the composition of the fluid.