Epoxy Adhesive Color Change Indicator for Curing Monitoring

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Solution Overview

Problem

Cold-curing two-component epoxy adhesives lack a clear method to determine when they are fully cured, as they do not exhibit visual changes during polymerization, making it difficult to assess their mechanical readiness for use and repositioning.

Innovation Solution

Incorporating a color change indicator, such as azo compounds or pH-dependent dyes like phenolphthalein, into the epoxy resin system, which changes color during curing, allowing users to monitor the progress and determine the end of the curing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a cold-curing two-component epoxy adhesive is used, then the adhesive can harden at room temperature without thermal curing, but it is impossible to visually determine the curing progress or endpoint

Engineering Contradiction:
Improvecuring temperatureVSAvoidcuring progress detection
Core Design Contradiction:
TemperatureVSDifficulty of detecting and measuring

Solution Approach 1:

The patent applies a color change indicator system to the epoxy adhesive composition. The indicator comprises a first indicator component and a second indicator component that interact to produce a visible color change during the curing process. This allows users to visually monitor the curing progress and determine when the adhesive has reached its endpoint, resolving the detection difficulty while maintaining cold-curing capability.

Inventive Principle:
Principle #32Color changes

2Measurement precision

If the hardness test is used to determine curing completion, then the curing endpoint can be assessed, but the test sensitivity is poor and requires destructive sampling

Engineering Contradiction:
Improvecuring completion assessmentVSAvoidtesting complexity
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The patent replaces the mechanical hardness testing method with a chemical indicator system. Instead of requiring physical contact and measurement tools to assess curing completion, the color change indicator provides a visual, non-contact method that is far more sensitive and easier to operate. The indicator system detects molecular-level changes in the curing process, providing superior measurement precision without the complexity of mechanical testing equipment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of operation

If no visual indicator is added to the adhesive, then the adhesive maintains its original composition and properties, but there is no way to monitor curing progress during application

Engineering Contradiction:
Improvecuring monitoring capabilityVSAvoidadhesive composition complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent introduces an intermediary indicator system that mediates between the chemical curing process and the user's visual observation. The indicator comprises two components that interact with each other and with the curing environment to produce a visible signal. This intermediary system allows monitoring of curing progress without fundamentally altering the adhesive's primary function or requiring complex instrumentation, adding only minimal compositional complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables users to easily identify when the adhesive has achieved final mechanical properties and reached the maximum working time, ensuring safe mechanical stress application without affecting the material's physical or mechanical properties.

Implementation Method 1

the color change indicator changes the epoxy adhesive from colorless or white to colored... the color change indicator comprises a color change indicator, demonstrating a pH dependency

Methodology Applied
Scientific EffectpH dependency:

Implementation Method 2

the color change indicator comprises an inorganic or organic dye, preferably including azo compounds or azo dyes

Methodology Applied
Scientific EffectAzo compound color change:

Data Source

PatentEP2748245B1Indicator for cure of two-component-epoxy adhesives
Publication Date: 2017.06.21 HENKEL KGAA

AI summary

The subject matter of the present application is a cold-curing two-component-epoxy adhesive, comprising: (a) an epoxy-resin-component and (b) a curing agent-component, comprising a mercaptan curing agent, in which the epoxy-resin-component comprises a color change indicator. Also described is a method for monitoring the curing progress of cold-curing two-component-epoxy adhesive via color change of the adhesive.